Skip to main content
SpringerLink
Log in

Crystallization kinetics of zeolite-like phosphates AIPO4-5 and SAPO-5

  • Published:
Theoretical and Experimental Chemistry Aims and scope

Abstract

We show that the crystallization rate of isostructural zeolite-like phosphates AlPO4-5 and SAPO-5 is considerably higher than for zeolites and polysilicates. We analyze the kinetic and energy parameters, taking into account the high structural lability of aluminophosphates, the effect of limiting processes of dissolution of the original pseudoboehmite and conversion of the intermediates, and also isomorphic inclusion of silicon atoms.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. T. Wilson and B. M. Lok, "Absorptive use of crystalline metallophosphate compositions," US Pat. 4,385,994; ICL3 B 01 D 15/00; Publ. 31.05.83.

  2. B. M. Lok, C. A. Messina, R. L. Patton, et al., "Crystalline silicoaluminophosphates," US Pat. 4,440,871; ICL3 B 01 J 27/14; Publ. 03.04.84.

  3. G. A. Dvoretskov, E. N. Kuznetsova, S. A. Ivanov, et al., Kolloidn. Zh.,52, No. 6, 1170 (1990).

    CAS  Google Scholar 

  4. B. Kanz-Reuschel, G. Finger, and J. Kornatowski, in: Proceedings, International Symposium on Zeolite Chemistry and Catalysis, Prague, September 8–13 (1991), p. 3.

  5. N. V. Turutina and V. G. Il’in, Ukr. Khim. Zh.,49, No. 7, 731–734 (1983).

    CAS  Google Scholar 

  6. A. N. Kolmogorov, Izv. Akad. Nauk SSSR, Ser. Mat., No. 3, 355 (1937).

  7. G. V. Sakovich, Ucheb. Zap. Tomsk. Univ., No. 26, 103 (1955).

  8. E. N. Eremin, Principles of Chemical Kinetics [in Russian], Vyssh. Shk., Moscow (1976).

    Google Scholar 

  9. T. Ito, N. Dumont, J. B. Nagy, et al., in: Proceedings, International Symposium on Chemistry of Microporous Crystals, Tokyo, June 26–29, 1990; Tokyo-Amsterdam (1991), p. 11.

  10. V. M. Chertov, V. I. Zelentsov, and R. S. Tyutyunnik, Adsorbtsiya Adsorbenty, No. 3, 33–36 (1975).

Download references

Authors
  1. P. S. Yaremov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. G. Il’in
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Nauki Prospekt, Kiev 252039, Ukraine. Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 33, No. 3, pp. 184–187. May–June, 1997.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yaremov, P.S., Il’in, V.G. Crystallization kinetics of zeolite-like phosphates AIPO4-5 and SAPO-5. Theor Exp Chem 33, 153–156 (1997). https://doi.org/10.1007/BF02765915

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02765915

Keywords

Search

Navigation