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Journal of Structural Chemistry

, Volume 38, Issue 3, pp 426–433 | Cite as

Synthesis and crystal structure of new complex oxides K10M2+Mo7O27 (M2+ = Mg, Mn, Co)

  • S. F. Solodovnikov
  • R. F. Klevtsova
  • L. A. Glinskaya
  • Z. A. Solodovnikova
  • E. S. Zolotova
  • P. V. Klevtsov
Article

Abstract

New compounds, K10M2+ Mo7O27 (M2+ = Mg, Mn, Co), have been synthesized and characterized. The compounds have an original structure, as established for the first two phases (orthorhombic, space group Pnm21, Z = 2, a = 18353 and 18.402, b = 7.889 and 7.931, c = 10.566 and 10.604 å, R = 0.0345 and 0.0609, respectively). A specific feature of the structure is isolated clusters consisting of face-sharing MoO6 and M2+O6 octahedra, each of the latter having six MoO4 tetrahedra attached to it by vertices. The general pseudohexagonal motif of the structure of the phases is similar to that of glaserites.

Keywords

Coordination Polyhedron CaMoO4 Potassium Atom Molybdenum Atom Equivalent Isotropic Thermal Parameter 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • S. F. Solodovnikov
    • 1
  • R. F. Klevtsova
    • 1
  • L. A. Glinskaya
    • 1
  • Z. A. Solodovnikova
    • 1
  • E. S. Zolotova
    • 1
  • P. V. Klevtsov
    • 1
  1. 1.Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesRussia

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