Skip to main content
SpringerLink
Log in

Physicochemical properties of pressure-synthesized lithium fullendes

  • Published:
Inorganic Materials Aims and scope

Abstract

LinC60 fullendes were prepared by high-pressure solid-state reactions and characterized by IR spectroscopy and x-ray diffraction. The results are interpreted in terms of a sequence of phase transformations induced by Li incorporation. At low Li contents, 2 <n < 3, a one-dimensional polymer with an orthorhombic structure is formed. Higher Li contents give rise to the formation of a mixture of dimeric and polymeric phases. At n = 5.7, only a dimeric phase with a triclinic structure is formed. In the range 7.1 <n < 10.1, the size of Li clusters increases and a dimeric monoclinic phase forms.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Marques, L., Hodeau, J.-L., Nunez-Regueiro, M., and Perroux, M., Pressure and Temperature Diagram of Polymerized Fullerite,Phys. Rev. B: Condens. Matter, 1996, vol. 54, no. 18, pp. 12633–12636.

    Google Scholar 

  2. Savchenkova, A.P., Avdeev, V.V., Zubareva, N.A.,et al., Physicochemical Properties of Lithium Fullerides,Zh. Fiz. Khim., 1998, vol. 72, no. 7, pp. 1324–1326.

    Google Scholar 

  3. Zubareva, N.A., Savchenkova, A.P., Mitronova, G.Yu.,et al.,Infrared Spectra of High-Temperature and High- Pressure Lin C 60 Phases,Neorg. Mater., 1998, vol. 34, no. 12, pp. 1444–1449 [Inorg. Mater. (Engl. Transi.), vol. 34, no. 12, pp. 1218–1221].

    Google Scholar 

  4. Mitronova, G.Yu., Savchenkova, A.P., Maiorova, A.F.,et al., Incorporation of Lithium in C60 from the Liquid or Solid Phase,Dokl. Akad. Nauk, 1996, vol. 348, no. 4, pp. 491–493.

    CAS  Google Scholar 

  5. Oszlanyi, G., Bortel, G., Faigel, G.,et al., Dimerization in KC60 and RbC60,Phys. Rev. B: Condens. Matter, 1995, vol. 51, no. 18, pp. 12 228–12 232.

    CAS  Google Scholar 

  6. Bondarenko, G.N., Nalimova, V.A., Fateev, O.V.,et al., Vibrational Spectra of Lithium Graphite Intercalation Compounds,Carbon, 1998, vol. 36, no. 7/8, pp. 1107–1112.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Moscow State University, 119899, Moscow, Russia

    N. A. Zubareva, G. Yu. Mitronova, Yu. A. Velikodnyi & V. V. Avdeev

Authors
  1. N. A. Zubareva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. Yu. Mitronova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. A. Velikodnyi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. V. Avdeev
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zubareva, N.A., Mitronova, G.Y., Velikodnyi, Y.A. et al. Physicochemical properties of pressure-synthesized lithium fullendes. Inorg Mater 36, 1118–1120 (2000). https://doi.org/10.1007/BF02758928

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02758928

Keywords

Search

Navigation