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Inorganic Materials

, Volume 36, Issue 11, pp 1118–1120 | Cite as

Physicochemical properties of pressure-synthesized lithium fullendes

  • N. A. Zubareva
  • G. Yu. Mitronova
  • Yu. A. Velikodnyi
  • V. V. Avdeev
Article

Abstract

LinC60 fullendes were prepared by high-pressure solid-state reactions and characterized by IR spectroscopy and x-ray diffraction. The results are interpreted in terms of a sequence of phase transformations induced by Li incorporation. At low Li contents, 2 <n < 3, a one-dimensional polymer with an orthorhombic structure is formed. Higher Li contents give rise to the formation of a mixture of dimeric and polymeric phases. At n = 5.7, only a dimeric phase with a triclinic structure is formed. In the range 7.1 <n < 10.1, the size of Li clusters increases and a dimeric monoclinic phase forms.

Keywords

Fullerene Molar Volume Orthorhombic Phase Triclinic Structure Monoclinic Cell 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2000

Authors and Affiliations

  • N. A. Zubareva
    • 1
  • G. Yu. Mitronova
    • 1
  • Yu. A. Velikodnyi
    • 1
  • V. V. Avdeev
    • 1
  1. 1.Moscow State UniversityMoscowRussia

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