Skip to main content
SpringerLink
Log in

Spectroscopic study of Co-doped BaTiO3 thin films

  • Published:
Inorganic Materials Aims and scope

Abstract

Co-doped BaTiO3 thin films with the perovskite structure were prepared by pyrolysis of metalorganic compounds. According to optical-absorption and luminescence data, the introduction of Co had an insignificant effect on the Curie temperatureT C of the films (about 120δC), presumably because of the competitive effects of the Co dopant, reducingT C , and the large compressive strain due to the thermal expansion mismatch, raisingT C . An absorption band tentatively attributed to a small-radius polaron was observed in the near-infrared spectral region.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Jona, F. and Shirane, G.,Ferroelectric Crystals, Oxford: Pergamon, 1962. Translated under the titleSegnetoelektricheskie kristally, Moscow: Mir, 1965.

    Google Scholar 

  2. Bursian, E.V.,Nelineinyi kristall titanat bariya (Nonlinear Crystal Barium Titanate), Moscow: Nauka, 1974.

    Google Scholar 

  3. Tsoufova, P., Arend, G., and Novak, I., Structural and Physical Properties of Co-Doped Barium Titanate Crystals,Kristallografiya, 1964, vol. 9, no. 1, pp. 113–115.

    Google Scholar 

  4. Kudzin, A.Yu., Dielectric Properties of Co-Doped Barium Titanate Crystals,Kristallografiya, 1962, vol. 7, no. 5, pp. 799–802.

    CAS  Google Scholar 

  5. Peraza, J., Tello, M.J., Becanegra, H., and Manas-Dias, J., Characteristic Behaviour of Spontaneous Polarization and Dielectric Constant of Barium Titanate Containing Cobalt Ions,Solid State Commun., 1998, vol. 26, no. 3, pp. 127–131.

    Article  Google Scholar 

  6. Glozman, I.A.,P’ezokeramika (Piezoceramics), Moscow: Energiya, 1972.

    Google Scholar 

  7. Gakh, S.G., Myasnikova, T.P., Bunina, O.A., and Yusman, T.A., Structure and Optical Properties of Thin Films of PbTiO3 and BaTiO3,Neorg. Mater., 1995, vol. 31, no. 3, pp. 373–376 [Inorg. Mater. (Engl. Transi.), vol. 31, no. 3, pp. 345–347].

    Google Scholar 

  8. Dudkevich, V.P. and Fesenko, E.G.,Fizika segnetoelektricheskikh plenok (Physics of Ferroelectric Films), Rostov-on-Don: Rostov. Gos. Univ., 1979.

    Google Scholar 

  9. Zametin, V.M., Yakubovskii, M.A., and Rabkin, L.M., Phase-Transition-Induced Anomalies in the Absorption Edge,Fiz. Tverd. Tela (Leningrad), 1979, vol. 21, no. 2, pp. 491–498.

    CAS  Google Scholar 

  10. Sacudo, T., Effect of Iron Group Ions on the Dielectric Properties of BaTiO3 Ceramics,J. Phys. Soc. Jpn., 1957, vol. 12, no. 9, p. 1050.

    Article  Google Scholar 

  11. Myasnikova, T.P., Gakh, S.G., and Evseeva, R.Ya., Optical Spectra and Phase Transitions of Fe- and Co-Doped Barium Titanate Crystals,Kristallografiya (in press).

Download references

Author information

Authors and Affiliations

  1. Research Institute of Physics, Rostov State University, pr. Stachki 194, 344090, Rostov-on-Don, Russia

    T. P. Myasnikova, S. G. Gakh & I. N. Zakharchenko

Authors
  1. T. P. Myasnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. G. Gakh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. N. Zakharchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Myasnikova, T.P., Gakh, S.G. & Zakharchenko, I.N. Spectroscopic study of Co-doped BaTiO3 thin films. Inorg Mater 36, 726–728 (2000). https://doi.org/10.1007/BF02758430

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02758430

Keywords

Search

Navigation