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Specific effects of propargyl alcohol and propargyl chloride on an iron electrode in inorganic acids

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Abstract

The effect of acetylenic compounds, namely, propargyl alcohol (PA) and propargyl chloride (PC), on electrode processes occurring on Armco iron in hydrochloric, sulfuric, phosphoric, and perchloric acids was studied with the use of potentiostatic polarization. In oxygen-containing acids with hydrophilic anions, PA and PC are hydrogenated, thus decreasing the cathodic overpotential and significantly retarding iron ionization, which causes pitting at a free corrosion potential. More hydrophobic Cl− anions increase the cathodic overpotential and hinder the hydrogenation process. Propargyl chloride inhibits electrode reactions and iron corrosion more effectively than does less hydrophobic PA.

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References

  1. Balezin, S.A., Podobaev, N.I., Voskresenskii, A.G., and Vasil’ev, V.V.,Trudy III mezhdunarodnogo kongressa po korrozii metallov (Proc. III Int. Congr. on Metal Corrosion), Moscow: Mir, 1966, vol. 2, p. 7.

    Google Scholar 

  2. Balezin, S.A., Belen'kii, S.M., Aronson, Yu.P.,et al., Zashch. Met., 1996, vol. 32, no. 4, p. 385.

    Google Scholar 

  3. Petrova, L.A. and Klyuchnikov, N.G.,Ingibitory korrozii metallov (Inhibitors of Metal Corrosion), Moscow: Mosk. Gos. Pedagog. Inst., 1965, p. 115.

    Google Scholar 

  4. Reshetnikov, S.M.,Ingibitory kislotnoi korrozii metallov (Inhibitors of Acid Corrosion of Metals), Izhevsk: Udmurtiya, 1980, p. 77.

    Google Scholar 

  5. Allabergenov, K.D. and Kurbanov, F.K.,Zashch. Met., 1979, vol. 15, no. 4, p. 472.

    CAS  Google Scholar 

  6. Putilova, I.N., Lolua, A.M., Suponitskaya, I.I.,et al., ibid.,, 1968, vol. 4, no. 4, p. 392.

    CAS  Google Scholar 

  7. Novikov, V.E., Voskresenskii, A.G., and Podobaev, N.I.,Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1971, vol. 14, no. 3, p. 386.

    CAS  Google Scholar 

  8. Freiman, L.I.,Itogi Nauki Tekh., Ser.: Korroz. Zashch. Korroz., Moscow: VINITI, 1985, vol. 11, p. 7.

    Google Scholar 

  9. Podobaev, N.I. and Avdeev, Ya.G.Zashch. Met., 1999, vol. 35, no. 5, p. 531.

    Google Scholar 

  10. Tomilov, A.P., Mairanovskii, S.G., Fioshin, M.Ya., and Smirnov, V.A.,Elektrokhimiya organicheskikh soedinenii (The Electrochemistry of Organic Compounds), Leningrad: Khimiya, 1968, p. 138.

    Google Scholar 

  11. Podobaev, N.I. and Avdeev, Ya.G.,Vliyanie anionov Cl − i serosoderzhashchikh soedinenii na tormozhenie propargilovym spirtom elektrodnykh reaktsii, protekayushchikh na zheleze v sernoi kislote (Effect of Cl− Anions and Sulfur? Containing Compounds on the Deceleration with Propargyl Alcohol of Electrode Reactions Occurring on Iron in Sulfuric Acid), Available from VINITI, 1999, Moscow, no. 2997-V-99.

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  1. Moscow State Pedagogical University, ul. Malaya Pirogovskaya 1, 119882, Moscow, Russia

    N. I. Podobaev & Ya. G. Avdeev

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  1. N. I. Podobaev
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  2. Ya. G. Avdeev
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Podobaev, N.I., Avdeev, Y.G. Specific effects of propargyl alcohol and propargyl chloride on an iron electrode in inorganic acids. Prot Met 36, 251–257 (2000). https://doi.org/10.1007/BF02758401

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  • DOI: https://doi.org/10.1007/BF02758401

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