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Distribution coefficients of impurities in cadmium fluoride

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Abstract

Experimental data on the liquidus curve in cadmium fluoride-metal fluoride systems were used to calculate the distribution coefficients of di- and trivalent impurities in CdF2. A similar method was proposed for calculating the distribution coefficient from solidus data. It was shown that the variations of the calculated distribution coefficients with the ionic radii of M2+ and R3+ are well fitted by Gaussians. Phase relations in the CdF2-rich part of the CdF2-InF3 system were studied by differential thermal analysis and x-ray diffraction.

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, 117333, Moscow, Russia

    S. P. Ivanov, I. I. Buchinskaya & P. P. Fedorov

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  1. S. P. Ivanov
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  2. I. I. Buchinskaya
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  3. P. P. Fedorov
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Ivanov, S.P., Buchinskaya, I.I. & Fedorov, P.P. Distribution coefficients of impurities in cadmium fluoride. Inorg Mater 36, 392–396 (2000). https://doi.org/10.1007/BF02758088

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  • DOI: https://doi.org/10.1007/BF02758088

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