Inorganic Materials

, Volume 36, Issue 4, pp 333–336 | Cite as

A macroscopic approach to the problem of heteroepitaxy

  • P. I. Ignatenko


Based on the concepts of classical nucleation theory, a macroscopic criterion of heteroepitaxy is derived for layer-substrate systems in which no intermediate phases are formed. The criterion relates the epitaxial growth temperature to the associated interfacial energies, lattice mismatch, elastic constants of the layer, and supersaturation of the parent phase with the deposited substance.


Supersaturation Epitaxial Layer Epitaxial Growth Lattice Mismatch Classical Nucleation Theory 
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  1. 1.
    Pashley, D.W., The Nucleation Growth Structure and Epitaxy of Thin Surface Films,Adv. Phys., 1965, vol. 14, no. 55, pp. 327–416.CrossRefGoogle Scholar
  2. 2.
    Palatnik, L.S. and Papirov, I.I.,Epitaksial’nye plenki (Epitaxial Layers), Moscow: Nauka, 1971.Google Scholar
  3. 3.
    Gebhardt, M., Epitaxy,J. Cryst. Growth, 1973, vol. 15, pp. 105–142.Google Scholar
  4. 4.
    Lewis, B., Physical Processes in Epitaxial Growth,Thin Solid Films, 1975, vol. 7, no. 3/4, pp. 179–217.Google Scholar
  5. 5.
    Sheftal’, R.N., Epitaxial Growth of Single-Crystal Films (Review Article),Rost Krist., 1974, vol. 10, pp. 48–61.Google Scholar
  6. 6.
    Handbook of Thin Film Technology, Maissel, L.I. and Glang, R., Eds., New York: McGraw-Hill, 1970. Translated under the titleTekhnologiya tonkikh plenok, Moscow: Sovetskoe Radio, 1977, vol. 1.Google Scholar
  7. 7.
    Chernov, A.A., Crystallization Processes,Sovremennaya kristallografiya (Modern Crystallography), Vainshtein, B.K., Chernov, A.A., and Shuvalov, L.A., Eds., Moscow: Nauka, 1980, vol. 3, p. 7.Google Scholar
  8. 8.
    Ievlev, V.M., Trusov, L.I., and Kholmyanskii, V.A.,Strukturnye prevrashcheniya v tonkikh plenkakh (Structural Transformations in Thin Films), Moscow: Metallurgiya, 1982.Google Scholar
  9. 9.
    Kukushkin, S.A. and Osipov, A.V., Thermodynamics and Kinetics of First-Order Phase Transitions on the Surface of Solids,Khim. Fiz., 1996, vol. 15, no. 9, pp. 5–103.Google Scholar
  10. 10.
    Dankov, P.D., Crystal-Chemical Mechanism of Interaction of the Crystal Surface with Foreign Elemental Particles,Zh. Fiz. Khim., 1946, vol. 20, pp. 853–867.Google Scholar
  11. 11.
    Van derMerwe, J.H., Interfacial Misfit and Bonding between Oriented Films and Their Substrates,SingleCrystal Films, Francombe, M.H. and Sato, H., Eds., New York: Macmillan, 1964. Translated under the titleMonokristallicheskie plenki, Moscow: Mir, 1966, pp. 172–201.Google Scholar
  12. 12.
    Bliznakow, G., Current Topics in the Theory of Epitaxy,Rost Krist., 1965, vol. 5, pp. 64–67.Google Scholar
  13. 13.
    Aleksandrov, L.N., Epitaxial Growth of Semiconductor Films: Thermodynamics and Kinetics, inProtsessy rosta i sinteza poluprovodnikovykh kristallov i plenok (Growth and Synthesis of Semiconductor Crystals and Films), Novosibirsk: Nauka, 1975, part 1, pp. 5–11.Google Scholar
  14. 14.
    Belyaev, A.P., Rubets, V.P., and Kalinkin, I.P., Initial Stages of II-VI Epitaxial Growth on Muscovite Substrates,Fiz., Tverd. Tela (S.-Peterburg), 1997, vol. 39, no. 2, pp. 382–396.Google Scholar
  15. 15.
    Palatnik, L.S., Fuks, M.Ya., and Kosevich, V.M.,Mekhanizm obrazovaniya i substruktura kondensirovannykh plenok (Growth Mechanism and Substructure of Condensed Films), Moscow: Nauka, 1972.Google Scholar
  16. 16.
    Hirth, J.P., On the Movement of Interface Dislocations during Diffusion,Single-Crystal Films, Francombe, M.H. and Sato, H., Eds., New York: Macmillan, 1964. Translated under the titleMonokristallicheskie plenki, Moscow: Mir, 1966, pp. 211–214.Google Scholar
  17. 17.
    Ignatenko, P.I., Kinetics of Chemoepitaxial Nucleation in the Course of Reaction Diffusion,Izv. Akad. Nauk SSSR, Met., 1982, no. 2, pp. 167–171.Google Scholar
  18. 18.
    Christian, J.W.,Theory of Transformations in Metals and Alloys, Oxford: Pergamon, 1975. Translated under the titleTeoriya prevrashchenii vmetallakh i splavakh, Moscow: Mir, 1978.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2000

Authors and Affiliations

  • P. I. Ignatenko
    • 1
  1. 1.Donetsk State UniversityDonetskUkraine

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