Skip to main content
SpringerLink
Log in

Lithium borosulphate glasses: an analysis of glass transition temperature results

  • Published:
Bulletin of Materials Science Aims and scope Submit manuscript

Abstract

Lithium borosulphate glasses have been prepared in three different series: (a) (42·5 −x)Li2O:57·5 B2O3:xLi2SO4; (b) 42·5Li2O: (57·5 −x)B2O3:xLi2SO4 and (c) 42·5Li2O:57·5B2O3:xLi2SO4. The glass transition temperature (T g) of these glasses has been analysed on the basis of the fraction of four coordinated boron which governs the glass structure. The analysis reveals that the addition of Li2SO4 in series (a) and (b) gives rise to increased value of N4 whereas, in series (c) it increases the number of non-bridging oxygens.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Bray P J and O’Keefe J G 1963Phys. Chem. Glasses 4 37

    Google Scholar 

  • Button D P, Tandon R P, King C, Velez M H, Tuller H L and Uhlmann D R 1982J. Non-Cryst. Solids 49 129

    Article  CAS  Google Scholar 

  • Button D P, Moon P K, Tuller H L and Uhlmann D R 1983Glastech. Ber. 56 K Bd 2 856

    Google Scholar 

  • Charles R J 1966J. Am. Ceram. Soc. 49 55

    Article  CAS  Google Scholar 

  • Deshpande V K, Rokade S and Singh K 1985Proc. Sixth Riso. Int. Symp. on transport-structure relationship in fast ion and mixed conductors, Denmark (eds) F W Poulsen, N H Andersen, K Clusen, S Skaarup and O T Sorensen; GH-Tryk 1/S Odense, 129

  • Gandhi P R, Deshpande V K and Singh K 1989Solid State Ionics 36 97

    Article  CAS  Google Scholar 

  • Ito Y, Miyauchi K and Oi T 1983J. Non-Cryst. Solids 57 389

    Article  CAS  Google Scholar 

  • Konijnedijk W N and Stevels J M 1975J. Non-Cryst. Solids 18 307

    Article  Google Scholar 

  • Kamitsos E I, Kavakassites M A and Chryssikos G D 1986J. Phys. Chem. 90 4528

    Article  CAS  Google Scholar 

  • Kamitsos E I, Kavakassites M A and Chryssikos G D 1987J. Phys. Chem. 91 5807

    Article  CAS  Google Scholar 

  • Levasseur A, Kabala M, Brethous J C and Hagenmullar P 1979aSolid State Commun. 32 839

    Article  CAS  Google Scholar 

  • Levasseur A, Brethous J C, Reau J M and Hagenmullar P 1979bMater. Res. Bull. 14 921

    Article  CAS  Google Scholar 

  • Otto K 1966Phys. Chem. Glasses 7 29

    CAS  Google Scholar 

  • Singh K and Rokade S 1984J. Power Sources 13 159

    Article  CAS  Google Scholar 

  • Soppe W, Marcel C V D and Hartog H W D 1988J. Non-Cryst. Solids 101 101

    Article  CAS  Google Scholar 

  • Takahashi T and Yamamoto O 1979Chem. Lett. 135

  • Tuller H L and Button D P 1985Proc. Sixth Riso. Int. Symp. on Transport-structure relationship in fast ion and mixed conductors, Denmark (eds) F W Poulsen, N H Andersen, K Clusen, S Skaarup and O T Sorensen; GH-Tryk 1/S Odense, 119

Download references

Author information

Authors and Affiliations

  1. Department of Physics, Nagpur University, 440 010, Nagpur, India

    P R Gandhi, V K Deshpande & K Singh

  2. Department of Physics, Visveraya Regional College of Engineering, 440 011, Nagpur, India

    V K Deshpande

Authors
  1. P R Gandhi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V K Deshpande
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K Singh
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gandhi, P.R., Deshpande, V.K. & Singh, K. Lithium borosulphate glasses: an analysis of glass transition temperature results. Bull. Mater. Sci. 15, 467–471 (1992). https://doi.org/10.1007/BF02745297

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02745297

Keywords

Search

Navigation