Bulletin of Materials Science

, Volume 19, Issue 4, pp 615–622 | Cite as

Effect of praseodymium substitution on the growth and properties of Y1−x Pr x Ba2Cu3O7−δ (o <x < 0·4) single crystals

  • Veer Singh
  • Subhash C Kashyap


In the present paper, a modified self-flux technique has been successfully employed for the growth of pure and praseodymium substituted (partially) large single crystals of high temperature superconducting Y1−x Pr x Ba2Cu3O7−δ (x = 0·0,0·2,0·4). Typical sizes of the platy and bulky crystals of pure YBCO(123) material are ≈ 2 × 2 × 0·1 mm3 and 4 × 1 × 1 mm3, respectively. In case of Pr-substitution, the typical sizes of platy and bulky crystals of Y0·8Pr0·2Ba2Cu3O7−δ and Y0·6Pr0·4Ba2Cu3O7−δ materials are ≈ 2 × 3 × 0·1 mm3 and 5 × 1 × 1 mm3 and ≈ 1 × 1·5 × 0·1 mm3 and 7 × 0·2 × 0·1 mm3, respectively. The morphology and growth habit of the as-grown single crystals and the critical transition temperature (T c) of the oxygenated crystals were found to depend on the Pr-content.


High temperature superconductor crystal growth Y1−xPrxBa2Cu3O7−δ 


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Copyright information

© the Indian Academy of Sciences 1996

Authors and Affiliations

  • Veer Singh
    • 1
  • Subhash C Kashyap
    • 1
  1. 1.Department of PhysicsIndian Institute of TechnologyHauz Khas, New DelhiIndia

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