Abstract
Thermal expansion data is reported over a wide temperature range (80–800 K) for BaTiO3 (BT) and Pb(Fe1/2 Nb1/2)O3 (PFN), belonging to different classes of the ferroelectric materials. The sharp structural phase transitions of BT result in lowering of the thermal expansion coefficient (α) at the transitions which is proportional to the change in polarization at the transitions. In PFN, a relaxor ferroelectric, lowering of α is spread over a wider temperature range across the dielectric maxima.
Similar content being viewed by others
References
Clabaugh W S, Swiggard E M and Gilchrist R 1956J. Res. Natl. Bur. Stand. 56 289
Cross L E 1994Ferroelectrics 151 305
Jaffe B, Cook W R and Jaffe H 1971Piezoelectric ceramics (London: Academic Press) p. 53
Jang S J, Uchino K, Nomura S and Cross L E 1980Ferroelectrics 27 31
Kay H F and Vousden P 1949Philos. Mag. 40 1019
Krishnan R S, Srinivasan R and Devanarayanan S 1979Thermal expansion of crystals; International series in: Science of the solid state (Pergamon Press) vol. 12
Megaw H D 1947Proc. R. Soc. London; Ser. A 189 261
Nomura S, Abe M, Kojima F and Uchino K 1975Jpn. J. Appl. Phys. 14 1881
Nomura S and Uchino K 1982Ferroelectrics 41 117
Radhika Rao M V, Halliyal A and Umarji A M 1996J. Am. Ceram. Soc. 79 257
Rhodes R G 1951Acta Crystallogr. 4 105
Sai Sundar V V S S and Umarji A M 1995Mater. Res. Bull. 30 427
Shirane G and Takeda A 1952J. Phys. Soc. Japan 7 1
Smolenskii G A 1984Ferroelectrics 53 129
Tsurumi T, Soejima K, Kamaya T and Daimon M 1994Jpn. J. Appl. Phys. 33 1959
Umarji A M, Senbhagaraman S and Radhika Rao M V 1997J. Instr. Soc. India 27
Yokosuka M 1993Jpn. J. Appl. Phys. 32 1142
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Radhika Rao, M.V., Umarji, A.M. Thermal expansion studies on ferroelectric materials. Bull Mater Sci 20, 1023–1028 (1997). https://doi.org/10.1007/BF02744891
Issue Date:
DOI: https://doi.org/10.1007/BF02744891