Abstract
Ceramics (Pb0·75Ca0·25)[(Ni1/2W1/2) y Ti1−y ]O3 fory = 0 ·05, 0·10, 0·15 and 0·30 have been prepared using high temperature solid state reaction method. X-ray analyses show that these materials are of single-phase perovskite type tetragonal structure. To solve inaccuracy in finding para-ferroelectric phase transition temperatureT c(ε max), we have carried out the analyses of the data using a computer program. The role of Ni and W as modifiers on structural and electrical (dielectric and pyroelectric) properties is discussed in terms of the usefulness of these materials. Results indicate that ceramic Pb0·75Ca0·25Ni0·25W0·025Ti0·95O3 is a good candidate for pyroelectric applications.
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References
Alemany C, Gallo J G, Jimenez B, Maurer E and Mendiola J 1984Ferroelectrics 54 137
Bayer R L and Roundy C B 1972Ferroelectrics 3 333
Burns G and Dacol F H 1985J. Appl. Phys. Japan Suppl. 24 85
Cohen Ronald E 1992Nature 358 136
del Olmo L, Pardo L, Pina J I, Fandiño C, Alemany C, Mendiola J, Jimenez B and Maurer E 1987 Patente Española de Invencion # 8603556
Fouskova A, Kohl V, Krainik N N and Mylnilova I E 1981Ferroelectrics 34 119
Halliyal A, Kumar U, Newnham R E and Cross L E 1987J. Am. Ceram. Soc. 70 119
Harada J, Pedersen T and Barnea Z 1970Acta Crystallogr. A26 608
Ichinose N 1985J. Am. Ceram. Soc. Bull. 64 1581
Jimenez B, Frutos J de and Alemany C 1987J. Phys. Chem. Solids 48 877
Kirsch B, Schmitt H and Müser H E 1986Ferroelectrics 68 275
Kuwata J, Uchino K and Nomura S 1982Jpn J. Appl. Phys. 21 1298
Mendiola J, Jimenez B, Alemany C, Pardo L and del Olmo L 1989Ferroelectrics 94 183
Nadoliisky M M, Vassileva T K and Yanehev R V 1991Ferroelectrics 118 111
Prasad K, Choudhary S N, Choudhary R N P and Yadav K L 1993aJ. Mater. Sci. Lett. 12 758
Prasad K, Sati R, Choudhary R N P and Sinha T P 1993bBull. Mater. Sci. 16 679
Prasad K, Singh N P, Choudhary R N P and Sati R 1994aIndian J. Pure & Appl. Phys. 32 764
Prasad K, Sati R, Choudhary R N P and Singh N P 1994bPhys. Status Solidi 143a 423
Prasad K, Choudhary R N P and Sati R 1995aProc. Indian Nat. Sci. Acad. PartA 61 337
Prasad K, Choudhary R N P and Sati R 1995bNat. Acad. Sci. Lett. 18 145
Srivastava C M and Srinivasan C 1991Science of engineering materials (New Delhi: Wiley Eastern Ltd.)
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Prasad, K., Choudhary, R., Choudhary, S. et al. On the structural and electrical properties of modified PbTiO3 ceramics. Bull. Mater. Sci. 19, 505–512 (1996). https://doi.org/10.1007/BF02744822
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DOI: https://doi.org/10.1007/BF02744822