Bulletin of Materials Science

, Volume 14, Issue 3, pp 697–702 | Cite as

Structural studies on Fe-substituted Y-Ba-Cu-O superconductors by Mössbauer spectroscopy

  • S Srinivasan
  • V Sridharan
  • T Nagarajan
International Conference On Superconductivity—II


In this paper we report preparation and structural aspects of YBa2Cu2·97Fe0·03O7−x with different oxygen stoichiometry. The samples were prepared by standard solid-state reaction. The samples were characterized by X-ray powder diffraction and oxygen contents were estimated from iodometric titration method. The superconducting transition temperatureT c is measured using the standard four-probe technique. Mössbauer studies of YBa2Cu2·97Fe0·03O7−x with different oxygen stoichiometry were carried out and the results show that Fe substitutes both Cu(2) and Cu(1) sites and clear asymmetry in the doublets except for the tetragonal case. Also our results show the progressive oxygenation inb-axis as oxygen stoichiometry is increased.


Oxygen stoichiometry structural studies Fe-substituted Y-Ba-Cu-O Mössbauer spectroscopy 


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Copyright information

© Indian Academy of Sciences 1991

Authors and Affiliations

  • S Srinivasan
    • 1
  • V Sridharan
    • 1
  • T Nagarajan
    • 1
  1. 1.School of PhysicsUniversity of MadrasMadrasIndia

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