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Conductivity pre-exponential factors for some new superionic conductors

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Abstract

The pre-exponential factors obtained from the ionic conductivity studies on Na2(La, Al)ZrP3O12, Na2(La, Al)TiP3O12, NH4Zr2V3O12 and AlPO4:Li+ have been analysed. The compensation law has been found to be valid for these materials indicating that the entropy is directly related to the activation energy. The 1/α vsβ plots show straight lines for most of the superionic materials except for a few and this variation has been discussed.

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Desai, N.B., Byrappa, K., Gopalakrishna, G.S. et al. Conductivity pre-exponential factors for some new superionic conductors. Bull. Mater. Sci. 9, 317–321 (1987). https://doi.org/10.1007/BF02744012

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  • DOI: https://doi.org/10.1007/BF02744012

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