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Journal of Structural Chemistry

, Volume 41, Issue 3, pp 463–467 | Cite as

Synthesis and crystal structure of sodiumtrans- nitrosoaquatetrachlororuthenate(II)

  • V. A. Emel'yanov
  • I. A. Baidina
  • S. A. Gromilov
  • A. V. Virovets
  • A. V. Belyaev
Article

Abstract

Synthesis of the compound NalRuNOCl4H2O] . 2H2O is reported. The complex was investigated by IR spectroscopy and X-ray phase and diffraction analyses. Crystal data: a = 7.0103(7), b = 11.133(1), c = 12.843(1) Å, β = 99.076(8)ℴ, V = 989.8(2) Å3, space group P2l/n, 2 = 4, dcalc = 2.348, dexp = 2.340 g/cm3. The structure consists of [ RUNOCI4H2O] complex onions, Na+ cations, and crystallization water molecules. The compound crystallizes as dark red concretions formed after prolonged storage of a saturated aqueous solution. The crystals are hygroscopic and spread when stored in air.

Keywords

Complex Anion Saturated Aqueous Solution Mother Solution Crystallization Water Molecule Nitroso Group 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Kluwer Academic/Plenum Publishers 2000

Authors and Affiliations

  • V. A. Emel'yanov
    • 1
  • I. A. Baidina
    • 1
  • S. A. Gromilov
    • 1
  • A. V. Virovets
    • 1
  • A. V. Belyaev
    • 1
  1. 1.Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesUSSR

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