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Journal of Structural Chemistry

, Volume 41, Issue 2, pp 280–284 | Cite as

A new type of mixed framework in the crystal structure of binary molybdate Nd2Zr3(MoO4)9

  • R. F. Klevtsova
  • S. F. Solodovnikov
  • Y. L. Tushinova
  • B. G. Bazarov
  • L. A. Glinskaya
  • Zh. G. Bazarova
Article

Abstract

Single crystals of binary molybdate Nd2ZrMoO4)9 were grown. The crystal structure of this compound was investigated by X-ray diffraction analysis (CAD-4 diffractometer, MoKα radiation, 2844 reflections. R = 0.0230), and a new type of structure was found. The crystals are trigonal with cell dimensions a = 9.804(1), c = 58.467(12) å, V= 4867(1) å3, Z = 6, dcalc = 4.098 g/cm3, space group R 3 c. The structure involves polyhedra of three types: MoO4 tetrahedra, ZrO6 octahedra, and NdO9 tricapped trigonal prisms linked by their common vertices into an original three-dimensional framework.

Keywords

Coordination Polyhedron Trigonal Prism Zirconium Atom Equivalent Isotropic Thermal Parameter Tricapped Trigonal Prism 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Kluwer Academic/Plenum Publishers 2000

Authors and Affiliations

  • R. F. Klevtsova
    • 1
    • 2
  • S. F. Solodovnikov
    • 1
    • 2
  • Y. L. Tushinova
    • 1
    • 2
  • B. G. Bazarov
    • 1
    • 2
  • L. A. Glinskaya
    • 1
    • 2
  • Zh. G. Bazarova
    • 1
    • 2
  1. 1.Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirsk
  2. 2.Baikal Institute of Nature Use, Siberian BranchRussian Academy of SciencesUlan-Ude

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