Advertisement

Journal of Structural Chemistry

, Volume 41, Issue 2, pp 238–242 | Cite as

Prephase state in 2-bromo-2-nitropropane-1,3-diol crystals: Structural aspects and IR spectra

  • N. I. Golovina
  • N. V. Chukanov
  • A. V. Raevskii
  • L. O. Atovmyan
Article

Abstract

This paper is a continuation of our series of publications dealing with crystal-lattice processes occuning on heating and at temperatures near the transition point and accompanied by structural changes in discrete molecules and in the crystal structure as a whole. The prephase state of 2-bromo-2-nitropropane-1,3-diol crystals and the transition from monoclinic to cubic phase are studied by IR spectroscopy at 296–391 K.

Keywords

Transition Point Nitro Group Intermolecular Hydrogen Bond Monoclinic Phase Lone Electron Pair 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    N. I. Golovina, A. V. Raevskii, B. S. Fedorov, et al.,J. Solid State Chem., 136 (1998).Google Scholar
  2. 2.
    B. S. Fedorov, N. I. Golovina, L. S. Barinova, et al.,Izv. Akad. Nauk SSSR, Ser. Khim., No. 10, 2372-2380 (1991).Google Scholar
  3. 3.
    A. V. Rakov.Opt. Spektrosk., No. 7, 202 (1959).Google Scholar
  4. 4.
    V. I. Vettegren, I. V. Dreval, V. E. Korsukov, and I. I. Novak,Vysokomolek. Soedin., Sci: B,12, 680 (1970).Google Scholar
  5. 5.
    B. Coen and S. Weiss,J. Phys. Chem.,88 No. 14, 3159–3162 (1984).CrossRefGoogle Scholar
  6. 6.
    R. V. Chukanov, L. V. Berlyand, B. L. Korsunskii, and V. A. Dubovitskii,Zh. Fiz. Khim.,64, No. 7, 1814–1819 (1990).Google Scholar
  7. 7.
    L. V. Berlyand. N. V. Chukanov, and V. A. Dubovitskii,Chem. Phys. Lett.,181, No. 5, 450–454 (1991).CrossRefGoogle Scholar
  8. 8.
    A. S. Rozenberg and N. V. Chukanov,Izv. Ross. Akad. Nauk, Ser. Khim., No. 2, 350-354 (1996).Google Scholar

Copyright information

© Kluwer Academic/Plenum Publishers 2000

Authors and Affiliations

  • N. I. Golovina
    • 1
  • N. V. Chukanov
    • 1
  • A. V. Raevskii
    • 1
  • L. O. Atovmyan
    • 1
  1. 1.Institute of Chemical Physics ProblemsRussian Academy of SciencesChernogolovka

Personalised recommendations