Skip to main content
SpringerLink
Log in

Infrared and Raman spectroscopic studies of glasses with NASICON-type chemistry

  • Published:
Journal of Chemical Sciences Aims and scope Submit manuscript

Abstract

Structures of NASICON glasses of the general formula AB2(PO4)3, where A = Li, Na or K and B = Fe, Ga, Ti, V or Nb, have been investigated using vibrational (IR and Raman) spectroscopies. Phosphate species appear to establish an equilibrium via a disproportionation reaction involving a dynamical bond-switching mechanism where both charge and bonds are conserved. B ions in the system acquire different coordinations to oxygens. Alkali ions cause absorptions due to cage vibrations. All the observed spectroscopic features are consistent with speciation involving disproportionation reactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Hong H Y-P 1976Mater. Res. Bull. 11 173

    Article  CAS  Google Scholar 

  2. Goodenough J B, Hong H Y-P and Kafalas J A 1976Mater. Res. Bull. 11 203

    Article  CAS  Google Scholar 

  3. Veríssimo C, Garrido F M S, Alves O L, Paloma Calle, Martínez-Juárez A, Iglesias J E and Rojo J M 1997Solid State Ionics 100 127

    Article  Google Scholar 

  4. Prakash G V, Nachimuthu P, Vithal M and Jagannathan R 1999Bull. Mater. Sci. 22 121

    Article  CAS  Google Scholar 

  5. Catti M 2001J. Solid State Chem. 156 305

    Article  CAS  Google Scholar 

  6. Sobha K C and Rao K J 1995Solid State Ionics 81 145

    Article  CAS  Google Scholar 

  7. Sobha K C and Rao K J 1995Proc. Indian Acad. Sci. (Chem. Sci.) 107 573

    CAS  Google Scholar 

  8. Sobha K C and Rao K J 1996J. Non-Cryst. Solids 201 52

    Article  CAS  Google Scholar 

  9. Sobha K C and Rao K J 1996J. Phys. Chem. Solids 57 1263

    Article  CAS  Google Scholar 

  10. Sobha K C and Rao K J 1996J. Solid State Chem. 121 197

    Article  CAS  Google Scholar 

  11. Boilot J P, Collin G and Comes R 1983J. Solid State Chem. 50 91

    Article  CAS  Google Scholar 

  12. Muthupari S and Rao K J 1994Chem. Phys. Lett. 223 133

    Article  CAS  Google Scholar 

  13. El Jazouli A, Parent C, Dance J M, Le Flem G, Hegenmuller P and Viala J C 1988J. Solid State Chem. 74 377

    Article  CAS  Google Scholar 

  14. Tarte P, Rulmont A, Liégeois-Duyckaerts M, Cahay R and Winand J M 1990Solid State Ionics 42 177

    Article  CAS  Google Scholar 

  15. Krimi S, El Jazouli A, Rabardel L, Couzi M, Mansouri I and Flem G Le 1993J. Solid State Chem. 102 400

    Article  CAS  Google Scholar 

  16. Wang B, Greenblatt M and Yan J 1994Solid State Ionics 69 85

    Article  CAS  Google Scholar 

  17. Berthet P, Bretey E, Berthon J, Yviore F d’, Belkebir A, Rulmont A and Gilbert B 1994Solid State Ionics 70/71 476

    Article  Google Scholar 

  18. Hagman L and Kierkegaard P 1968Actachem. Scand. 22 1822

    Article  CAS  Google Scholar 

  19. Barj M, Perthuis H and Colomban Ph 1983Solid State Ionics 9&10 845

    Article  Google Scholar 

  20. Barj M, Perthuis H and Colomban Ph 1983Solid State Ionics 9&10 157

    Article  Google Scholar 

  21. Tarte P, Rulmont A and Merckaert-Ansay C 1986Spectrochim. Acta A42 1009

    Google Scholar 

  22. Rochère M de la, Yvoire F d’, Collin G, Comès R and Boilot J P 1983Solid State Ionics 9&10 825

    Google Scholar 

  23. Corbridge D E C and Lowe E J 1954J. Chem. Soc. 493

  24. Exarhos G J and Risen W M Jr. 1972Solid State Commun. 11 755

    Article  CAS  Google Scholar 

  25. Exarhos G J, Miller P J and Risen W M Jr. 1974J. Chem. Phys. 60 4145

    Article  CAS  Google Scholar 

  26. Osaka A, Takahashi K and Ikeda M 1984J. Mater. Sci. 3 36

    CAS  Google Scholar 

  27. Wong J and Angell C A1976Glass structure by spectroscopy (New York: Marcel Dekker)

    Google Scholar 

  28. Moguš-Milanko’vic A, Pivac B, Fúric and Day D E 1997Phys. Chem. Glasses 38 74

    Google Scholar 

  29. Pivac B, Moguš-Milanko’vic A and Day D E 1998J. Non-Cryst. Solids 226 41

    Article  CAS  Google Scholar 

  30. Botto I L and Minelli G 1986J. Phys. Chem. Solids 47 259

    Article  CAS  Google Scholar 

  31. Sanderson R T 1983Polar covalence (New York: Academic Press)

    Google Scholar 

  32. Sales B C and Chakoumakos B C 1993J. Solid State Chem. 105 406

    Article  CAS  Google Scholar 

  33. Sakka S, Kozuka H, Fukumi K and Miyaji F 1990J. Non-Cryst. Solids 123 176

    Article  CAS  Google Scholar 

  34. Tourtin F, Armand P, Ibanez A, Manteghetti A and Philippot E 1997Thin Solid Films 307 43

    Article  CAS  Google Scholar 

  35. Tourtin F, Armand P, Ibanez A, Tourillon G and Philippot E 1998Thin Solid Films 322 85

    Article  CAS  Google Scholar 

  36. Nishida T, Shiotsuki T and Takashima Y 1981J. Non-Cryst. Solids 43 115

    Article  CAS  Google Scholar 

  37. Nelson C and Tallant D R 1985Phys. Chem. Glasses 26 119

    CAS  Google Scholar 

  38. Nelson B N and Exarhos G J 1979J. Chem. Phys. 71 2739

    Article  CAS  Google Scholar 

  39. Gabelica-Robert M and Tarte P 1982J. Mol. Struct. 79 251

    Article  CAS  Google Scholar 

  40. Ananthraj S and Rao K J 1991Proc. Indian Acad. Sci. (Chem. Sci.) 103 655

    CAS  Google Scholar 

  41. Bobovich Ya S 1962Opt. Spectrosc. 13 274

    Google Scholar 

  42. Furukawa T and White W B 1979Phys. Chem. Glasses 20 69

    CAS  Google Scholar 

  43. Verweij H and Buster J H J M 1979J. Non-Cryst. Solids 34 81

    Article  CAS  Google Scholar 

  44. Kumar S, Murugavel S and Rao K J 2001J. Phys. Chem. B105 5862

    Google Scholar 

  45. Muthupari S, Prabakar S and Rao K J 1994J. Phys. Chem. 98 2646

    Article  CAS  Google Scholar 

  46. Prabakar S, Rao K J and Rao C N R 1991J. Mater. Res. 6 285

    Google Scholar 

  47. Prabakar S, Rao K J and Rao C N R 1991Mater. Res. Bull. 26 805

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Solid State and Structural Chemistry Unit, Indian Institute of Science, 560 012, Bangalore, India

    K. J. Rao, K. C. Sobha & Sundeep Kumar

Authors
  1. K. J. Rao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. C. Sobha
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Sundeep Kumar
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to K. J. Rao.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rao, K.J., Sobha, K.C. & Kumar, S. Infrared and Raman spectroscopic studies of glasses with NASICON-type chemistry. J Chem Sci 113, 497–514 (2001). https://doi.org/10.1007/BF02708786

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02708786

Keywords

Search

Navigation