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Journal of Chemical Sciences

, Volume 113, Issue 1, pp 21–27 | Cite as

Synthetic, spectral and solution studies on imidazolate-bridged copper(II)-copper(II) and copper(II)-zinc(II) complexes

  • Subodh Kumar
  • R N Patel
  • P V Khadikar
  • K B PAndeya
Article

Abstract

Synthesis, spectral and solution studies on 2-ethyl imidazolate-bridged (2-EtIm) homo-binuclear copper(II)-copper(II) and hetero-binuclear copper(II)-zinc(II) homologue are described. Magnetic moment values of homo-binuclear complexes indicate that the imidazolate group can mediate antiferromagnetic interactions. Optical spectra of hetero-binuclear complex at varying pH values suggest that the imidazolate-bridged complex is stable over the pH-range 7.15–10.0.

Keywords

2-Ethylimidazolate-bridged homo/hetero-binuclear complexes anti-ferromagnetic interactions 

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Copyright information

© Indian Academy of Sciences 2001

Authors and Affiliations

  • Subodh Kumar
    • 1
  • R N Patel
    • 1
  • P V Khadikar
    • 1
  • K B PAndeya
    • 2
  1. 1.Department of ChemistryAPS UniversityRewaIndia
  2. 2.CSJM UniversityKanpurIndia

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