Abstract
The metal carbonate, MCO3 (M = Ca, Sr and Ba), was synthesized by a novel method of reacting aqueous solution of each of Ca2+, Sr2+ and Ba2+ salts with urea at high temperature, ∼ 80°C. The reaction products were characterized through elemental analysis and infrared spectra. The infrared spectra of the products are the same as those of the corresponding commercially obtained carbonates. A general reaction describing the formation of MCO3 is proposed.
Similar content being viewed by others
References
Arternova O E, Orlova V T and Lepeshkov L N 1985Russ. J. Inorg. Chem. 30 4
Barbier J P and Hugel R J 1974Inorg. Chim. Acta 10 93
Barbier J P and Hugel R J 1977J. Inorg. Nucl. Chem. 39 2283
Cotton F A and Wilkinson G 1980Advanced inorganic chemis- try (New York: John Wiley & Sons) 4th ed.
Hubberstey P 1988Coord. Chem. Rev. 85 86
Nakamoto K 1978Infrared and Raman spectra of inorganic and coordination compounds (New York: Wiley) 2nd ed
Nour E M and Rady A H 1991Trans. Met. Chem. 16 400
Nour E M, Teleb S M, Al-Khsosy N and Refat M S 1997Synth. React. Inorg. Met.-Org. Chem. 27 505
Penland R B, Mizushima S, Curran C and Quagliano J V 1957J. Am. Chem. Soc. 79 1575
Schafer M and Curran C 1966Inorg. Chem. 5 256
Srivastava P C and Aravindakshan C 1983Z. Phys. Chem. Leipzig 264 61
Teleb S M 1993Thermochim. Acta 228 131
Teleb S M, Sadeek S A and Nour E M 1993J. Phys. Chem. Solids 54 489
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Teleb, S.M., Nassr, D.ES. & Nour, E.M. Synthesis and infrared spectra of alkaline earth metal carbonates formed by the reaction of metal salts with urea at high temperature. Bull Mater Sci 27, 483–485 (2004). https://doi.org/10.1007/BF02707272
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02707272