Skip to main content
Log in

Simultaneous experiments of sulfidation and regeneration in two pressurized fluidized-bed reactors for hot gas desulfurization of IGCC

  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Hot Gas Desulfurizarion for IGCC is a new method to efficiently remove H2S in fuel gas with regenerable sorbents at high temperature and high-pressure conditions. The Korea Institute of Energy Research did operation of sulfidation in a desulfurizer and regeneration in a regenerator simultaneously at high pressure and high temperature conditions. The H2S concentration at exit was maintained continuously below 50ppmv at 11,000 ppmv of inlet H2S concentration. The sorbent had little effect on the reducing power in the inlet gas in the range from 11% to 33% of H2. As inlet H2S concentration was increased, H2S concentration in the product gas was also increased linearly. The sorbent was maintained at low sulfur level by the continuous regeneration and the continuous solid circulation at the rate of 1.58× 10−3 kg/s with little mean particle size change.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Abbasian, J. and Slimane, R. B., “A Regenerable Copper-Based Sorbent for H2S Removal from Coal Gases,”Ind. Eng. Chem. Res.,37, 2775 (1998).

    Article  CAS  Google Scholar 

  • Alonso, L., Palacios, J. M., Garcia, E. and Moliner, R., “Characterization of Mn and Cu Oxides as Regenerable Sorbents for Hot Coal Gas Desulfurization,”Fuel Processing Tech.,62, 31 (2000).

    Article  CAS  Google Scholar 

  • Choi, Y. C., Park, T. J., Kim, J. H., Lee, J. G., Hong J. C. and Kim Y. G., “Experimental Studies of 1 Ton/Day Coal Slurry Feed Type Oxygen Blown Entrained Flow Gasifierf”Korean J. Chem. Eng,18, 493 (2001).

    Article  CAS  Google Scholar 

  • Gangwal, S. K., Harlans, S. M., Woods, M. C., Jain, S. C. and Bossart, S. J., “Bench-Scale Testing of High-Temperature Desulfurization Sorbents,”Environ. Prog,8, 265 (1989).

    Article  CAS  Google Scholar 

  • Gasper-Galvin, L. D., Atimay, A. T. and Gupta, R. P., “Zeolite-Supported Metal Oxide Sorbents for Hot-Gas Desulfurization,”Ind. Eng. Chem. Res.,37, 4157 (1998).

    Article  CAS  Google Scholar 

  • Jothimurugesan, K. and Gangwal, S. K., “Regeneration of Zinc Titanate H2S Sorbents,”Ind. Eng. Chem. Res.,37, 1929 (1998).

    Article  CAS  Google Scholar 

  • Lee, T. J., Won, W T., Chang, W. C. and Kim, J. C., “A Study on Regeneration of Zinc Titanate Sorbents for H2S Removal,”Korean J. Chem. Eng.,14, 513 (1997).

    Article  CAS  Google Scholar 

  • Lee, Y. S., Park, D. H., Kim, H. T. and Yoo, K. O., “Oxidative Regeneration of Sulfided Sorbent by H2S without Emission of SO2,”Korean J. Chem. Eng,12, 23 (1995).

    Article  CAS  Google Scholar 

  • Li, Z. and Flyteani-Stephanopoulos, M, “Cu-Cr-O and Cu-Ce-O Regenerable Oxide Sorbents for Hot Gas Desulfurization,”Ind. Eng. Chem. Res.,36, 187 (1997).

    Article  CAS  Google Scholar 

  • Lim, C. J., Cha, Y K., Park, N. K., Ryu, S. O., Lee, T. J. and Kim, J. C., “A Study of Advanced Zinc Titanate Sorbent for Mid-Temperature Desulfurization,”HWAHAK GONGHAK,38, 111 (2000).

    CAS  Google Scholar 

  • Merrick, D. and Highley, J., “Particle Size Reduction and Elutriation in a Fluidized Bed Process,”AIChE Symp. Ser,70, 366 (1974).

    Google Scholar 

  • Park, J., Kim, J., Cho, S. H., Han, K. H., Yi, C. K. and Jin, G. T., “Development of Sorbent Manufacturing Technology by Agitation Fluidized Bed Granulator,”Korean J. Chem. Eng,16, 659 (1997).

    Article  Google Scholar 

  • Song, Y K., Lee, K. B., Lee, H. S. and Rhee, Y W, “Reactivity of Copper Oxide-Based Sorbent in Coal Gas Desulfurization,”Korean J. Chem. Eng,17, 691 (2000).

    Article  CAS  Google Scholar 

  • Woods, M. C., Gangwal, S. K., Jothimurugesan, K. and Harrison, D. P., “Reaction between H2S and Zinc Oxide-Titanium Oxide Sorbents,”Ind. Eng. Chem. Res.,29, 1160 (1990).

    Article  CAS  Google Scholar 

  • Yi, C. K., Han, K. H., Cho, S. H., Jin, G. T., Shun, D., Bae, D. H., Son, J. E., Kim, J. Y., Wi, Y. H., Lee, J. S. and Lee, J. B., “Hot Gas Desulfurization and Apparatus to Remove Hydrogen Sulfide at High Temperature and High Pressure from Coal Gases,” Korea Patent No. 0219366 (1999a).

  • Yi, C. K., Bae, D. H., Shun, D., Jin, G. T. and Son, J. E., “Pressure Balance Curves in KIER Solid Circulating Fluidized Process with Two Loopseals,”HWAHAK GONGHAK,37, 604 (1999b).

    CAS  Google Scholar 

  • Yi, C. K. and Luyben, W. L., “Dynamic Model and Control Structures for a Hot-Gas Desulfurization Fluidized Process,”Ind. Eng. Chem. Res.,38, 4290 (1999).

    Article  CAS  Google Scholar 

  • Yi, C. K., Jo, S. H., Bae, D. H., Shun, D., Jin, G. T. and Son, J. E., “Particle Hold-up in the Two Fluidized Reactor System with Two Loop-seals,”J. Chem. Eng. Japan,34, 269 (2001).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Chang-Keun Yi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yi, CK., Jo, SH., Lee, BH. et al. Simultaneous experiments of sulfidation and regeneration in two pressurized fluidized-bed reactors for hot gas desulfurization of IGCC. Korean J. Chem. Eng. 18, 1005–1009 (2001). https://doi.org/10.1007/BF02705633

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02705633

Key words

Navigation