A non-linear mirror consisting of a lithium triborate crystal and a dichroic output coupler are used to mode-lock (passively) an Nd : YVO4 laser, pumped by a diode laser array. The laser can operate both in cw mode-locked and simultaneously Q-switched and mode-locked (QML) regime. The peak power of the laser while operating in QML regime is much higher but pulses suffers from poor amplitude stability. The incorporation of an acousto-optic modulator as an active Q-switch enhances the stability of the QML pulse envelope. The second-order non-linearity of powdered crystalline urea is conclusively measured with respect to KDP while the laser is operating in passively Q-switched and passively mode-locked regime as well as in actively Q-switched and passively mode-locked regime.