Analysis of stainless steel samples by energy dispersive X-ray fluorescence (EDXRF) spectrometry
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A simple method for the analysis of stainless steel samples is presented which is based on radioisotope excited energy dispersive X-ray fluorescence (EDXRF) spectrometry and does not require any type-standards. Both absorption and enhancement effects have been taken into account in the fundamental parameter method for quantitative analysis and an iterative approach is followed for calculation of concentrations in steel samples. Non-linear least square fitting (NL-LSF) procedures have been used to determine accurately the fluorescent peak intensities. The method has been tested by analysing several CRM standard reference samples and 304 and 316 steel samples assuming as unknown. The EDXRF results have also been compared with the results of analysis of same samples by vacuum emission spark spectrometry (VES). Obtained values for concentration in steel samples match quite well with their certified values.
KeywordsXRF spectrometry least squares fitting stainless steel
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- Claisse F and Quintin M 1967Can. Spectrosc. 12 129Google Scholar
- Lachance G R and Traill R J 1966Can. Spectrosc. 11 43Google Scholar
- McMaster W H, Delgrande N K and Hubbell J H 1969Compilation of X-ray cross sections, UCRL-50174 (Livermore: Lawrence Radiation Laboratory, Univ. California) p. 353Google Scholar
- Sawhney K J S, Tiwari M K, Singh A K and Nandedkar R V 1998Proc. 6th national seminar on X-ray spectroscopy and allied areas (eds) S K Joshiet al (New Delhi: Narosa) p. 130Google Scholar
- Sparks C J Jr 1975Adv. X-ray Anal. 19 19Google Scholar
- Tiwari M K and Sawhney K J S 2000 CATXRF: A quantitative analysis program for EDXRF spectrometry, CAT technical reportGoogle Scholar
- Van Grieken R E and Markowicz A A 1993Handbook of X-ray spectrometry (New York: Marcel Dekker) p. 181Google Scholar