Abstract
A new method is proposed for predicting the ō-phase susceptibility of high-temperature superalloys. It is based on modifications of previous methods which involve electron-vacancy correlations. A calculated critical electron-vacancy number unique to each residual matrix composition is compared to the total electron-vacancy concentration (N V) for the residual matrix. The new method has been applied to experimentally determined residual matrix compositions (i.e. the composition of a matrix after all early precipitates have formed) of nickel-and cobalt-base superalloys. The modification exhibits a greater range of applicability to various austenitic alloy compositions than do current electron-vacancy tools.
Similar content being viewed by others
References
R. L. Dreshfield:Met. Trans., 1971, vol. 2, pp. 1341–46.
H. J. Beattie Jr. and W. C. Hagel:Trans. TMS-AIME, 1965, vol. 233, pp. 277–87.
C. T. Sims:J.Metals, 1969, vol. 21, no. 12, pp. 2742.
E.W. Ross:J. Metals, 1967, vol. 19, no. 12, pp. 12–14.
R. L. Dreshfield and R. L. Ashbrook:NASA TND-5185, Washington, D.C., 1969.
W. L. Boesch and J. S. Slaney:Metal Progr., 1964, vol. 86, pp. 109–11.
L. R. Woodyat, C. T. Sims, and H. J. Beattie Jr.:Trans. TMS-AIME, 1966, vol. 236, pp. 519–27.
International Symposium on Structural Stability in Superalloys, vols, I and II, Seven Springs, Pa., September 4–6,1968.
S. Rideout, W. D. Manly, E. L. Kamen, B. S. Lement, and P. A. Beck:AIME Trans., 1951, vol. 191, pp. 872–76.
P. Greenfield and P. A. Beck:AIME Trans., 1954, vol. 200, pp. 253–57.
H. J. Murphy, C. T. Sims, and A. M. Beltran:J. Metals, 1968, vol. 20, no. 12, pp. 46–54.
J. R. Mihalisin and D. L. Pasquine:International Symposium on Structural Stability in Superalloys, pp. 134–71, Seven Springs, Pa., 1968.
O. H. Kriege and J. M. Baris:Trans. ASM, 1969, vol. 62, pp. 195–200.
M. Hansen and P. Anderko:Constitution of Binary Alloys, 2nd ed., McGraw-Hill Book Co., New York, 1958.
R. P. Elliott:Constitution of Binary Alloys, First Supplement, McGraw-Hill Book Co., New York, 1965.
F. A. Shunk:Constitution of Binary Alloys, Second Supplement, McGraw-Hill Book Co., New York, 1969.
H. E. Collins and C. S. Kortovich:J. Mater., March 1969, vol. 4, no. 1, pp. 62–91.
C. B. Shoemaker and D. P. Shoemaker: inDevelopments in the Structural Chemistry of Alloy Phases, B. C. Giessen, ed., p. 107, Plenum Press, New York, 1969.
Author information
Authors and Affiliations
Additional information
R. G. BARROWS, formerly Graduate Research Assistant, University of Denver, Denver, Colorado 80210
Rights and permissions
About this article
Cite this article
Barrows, R.G., Newkirk, J.B. A modified system for predicting σ formation. Metall Trans 3, 2889–2893 (1972). https://doi.org/10.1007/BF02652857
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF02652857