Abstract
The amounts of formaldehyde-condensable polyphenols extracted from Pinus pinaster bark through alkaline lixiviations performed under different operational conditions are determined. Under the best conditions, both the losses of polysaccharides from the solid phase and the additional extracted polyphenols, coupling two stages of alkaline lixiviation, are evaluated. The effect of particle size on kinetics and yields of the lixiviations is determined.
Zusammenfassung
Die Mengen formaldehyd-kondensierbarer Polyphenole, die aus Pinus pinaster Rinde durch Alkali-Extraktion unter verschiedenen Arbeitsbedingungen gewonnen werden konnten, wurden bestimmt. Unter den jeweils günstigsten Bedingungen wurden die Verluste an Polysacchariden der festen Phase und die zusätzlich gelösten Polyphenole aus einer zweistufigen Alkali-Extraktion gemessen. Der Einfluß der Partikelgröße auf den Verlauf und die Ausbeute der Extraktion wurden untersucht.
Similar content being viewed by others
Literature
Anderson, S. B.; Wu, K. T.; Wong, A. 1974: Utilization of Ponderosa pine bark and its extracts in particleboards. Forest Prod. J. 24:48–53
Anderson, A.B. 1977: Bark extracts as bonding agent for particleboard. In: Goldstein, I.S. (Ed.) ACS Symp. Ser. No. 43, pp. 235–42 Am. Chem. Soc.
Ayla, C.; Weissman, G. 1981: Utilization of polyphenols, from Pinus brutia bark for the production of wood adhesives. Holz Roh Werkstoff 39:91–95
Ayla, C.; Weissman, G. 1982: Gluing tests with tannin formaldehyde resins from bark extracts of Pinus brutia ten. Holz Roh-Werkstoff 40:13–18
Browing, B. L.; Sell, L. O. 1957: The analysis of some fractions of slash pinc bark. TAPPI 40:362–65
Chang, Y. P.; Mitchell, R. L. 1955: Chemical composition of common North American pulpwood barks. TAPPI 38:315–20
Dix, B.; Marutzky, R. 1983: On the extraction of polyphenols from softwood barks. Holz Roh- Werkstoff 41:45–50
Hall, R. B.; Leonard, J. H.; Nicholls, G. A. 1960: Bonding particleboards with bark extracts. Forest Prod. J. 10:263–72
Hemingway, R. W. 1978: Adhesives from southern pine bark. A review of past and current approaches to resin formulation problems. In: McMillin, C. W. (Ed.): Complete tree utilization of southern pine. Proc. Symp., pp. 443–57. Medison: Forest Prod. Res. Soc.
Shah, R. B.; Clausen, E. C.; Gaddy, J. L. 1984: Production of chemical feedstocks from biomass. Chem. Eng. Prog. 1:76–80
Somogyi, M. 1952: Notes on sugar determination. J. Biol. Chem. 195:19–23
Vázquez, G.; Antorrena, G.; Parajó, J.C. 1985a. Studies on the utilization of Pinus pinaster bark. I. Chemical constituents. Wood Sci. Technol. (accepted for publication)
Vázquez, G.; Antorrena, G.; Parajó, J. C. 1985b: Studies on the tutilization of Pinus pinaster bark. I. Kinetics and yields of alkaline lixiviations. Wood Sci. Technol. (accepted for publication)
Weissman, G.; Ayla, C. 1980a: Utilization of natural polyphenols for the production of wood adhesives. Holz Roh Werkstoff 38:245–49
Weissman, G.; Ayla, C. 1980b: Investigation of extractives of Pinus brutia bark. Holz Roh- Werkstoff 38:307–12
Wissing, A. 1955: The utilization of bark. II. Investigation of the Stiasny reaction for the precipitation of polyphenols in pine bark extractives Svensk. Papperstidn. 20:745–50.
Yazaki, Y.; Hillis, W. E. 1977: Polyphenolic extractives of Pinus radiata bark. Holzforschung 31:20–25
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Vázquez, G., Antorrena, A. & Parajó, J.C. Selection of operational conditions in alkaline lixiviation of Pinus pinaster bark. Holz als Roh-und Werkstoff 44, 415–418 (1986). https://doi.org/10.1007/BF02609635
Issue Date:
DOI: https://doi.org/10.1007/BF02609635