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Novel derivatives of methyl hexahydro-3-methyl-6-thioxo-1,2,4,5-tetrazine-3-nonanoate

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Journal of the American Oil Chemists’ Society

Abstract

Methyl hexahydro-3-methyl-6-thioxo-1,2,4,5-tetrazine-3-nonanoate (I) on treatment with reagents such as chloroacetic acid, 1,2-dibromoethane and 2-mercaptoethanol under different reaction conditions afforded methyl 3,4,6,7-tetrahydro-3-methyl-6-oxo-2H-thiazolo[3,2-b]-1,2,4,5-tetrazine-3-nonanoate (II), methyl 3,4,6,7-tetrahydro-3-methyl-2H-thiazolo[3,2-b]-1,2,4,5-tetrazine-3-nonanoate (III) and methyl 8-methyl-1-oxa-4-thia-6,7,9,10-tetraazaspiro-[4.5]-decane-8-nonanoate (IV) in good yields. The structures of compounds II–IV were established by elemental analysis, infrared (IR), nuclear magnetic resonance (NMR), and mass spectral data.

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Authors and Affiliations

  1. Section of Oils and Fats, Department of Chemistry, Aligarh Muslim University, 202 002, Aligarth, India

    M. T. Saeed & S. M. Osman

  2. Applied Sciences Section, University Polytechnic, Faculty of Engineering and Technology, Aligarh Muslim University, 202 002, Aligarth, India

    J. Mustafa & A. Rauf

Authors
  1. M. T. Saeed
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  2. J. Mustafa
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  3. A. Rauf
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  4. S. M. Osman
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Saeed, M.T., Mustafa, J., Rauf, A. et al. Novel derivatives of methyl hexahydro-3-methyl-6-thioxo-1,2,4,5-tetrazine-3-nonanoate. J Am Oil Chem Soc 69, 481–484 (1992). https://doi.org/10.1007/BF02540954

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  • DOI: https://doi.org/10.1007/BF02540954

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