Abstract
A new reaction of benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone with amines that takes place with opening of one of the thiophene rings and nucleophilic substitution in the heteroaromatic ring at the site of cleavage of the S-C bond was observed. The molecular structures of the products of amination of the disulfone were determined by x-ray diffraction analysis. Hydrolysis and dehydration of the amination products gave derivatives of a new heterocyclic system, viz., benzo[b]-thieno[3,2-e]benzo[c]-1,2-oxathiin.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 320–323, March, 1980.
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Udre, V.É., Lukevits, É.Y., Kemme, A.A. et al. New reaction of benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone. Chem Heterocycl Compd 16, 234–237 (1980). https://doi.org/10.1007/BF02401716
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DOI: https://doi.org/10.1007/BF02401716