Abstract
The reaction of tetrachloroethylene with hydrogen sulfide at 450–500 °C leads to the formation of tetrachlorothiophene as the principal product, along with hexachlorobutadiene, the yield of which increases as the reaction temperature is raised.
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É. N. Sukhomazova, É. N. Deryagina, and M. G. Voronkov, Zh. Org. Khim.,16, No. 2 (1980).
M. G. Voronkov, É. N. Deryagina, M. A. Kuznetsova, and I. D. Kalikhman, Zh. Org. Khim.,14, 185 (1978).
E. R. Osgood, L. E. Limpel, R. R. Annis, and N. J. Tunner, US Patent No. 3354179 (1967); Chem. Abstr.,68, 104965 (1968).
R. H. Goshorn and J. E. Deger, US Patent No. 3350410 (1967); Chem. Abstr.,68, 95668 (1968).
M. G. Voronkov, É. N. Deryagina, L. G. Klochkova, and A. S. Nakhmanovich, Zh. Org. Khim.,12, 1515 (1976).
M. G. Voronkov, É. N. Deryagina, and V. I. Perevalova, USSR Inventor's Certificate No. 536677 (1976); Byul. Izobr., No. 1, 262 (1979).
M. G. Voronkov, É. N. Deryagina, and G. M. Ivanova, Zh. Org. Khim.,12, 2179 (1976).
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Communication 15 from the series “High-Temperature Organic Synthesis.” See [1] for communication 14.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 310–311, March, 1980.
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Voronkov, M.G., Deryagina, É.N. & Perevalova, V.I. New method for the synthesis of tetrachlorothiophene. Chem Heterocycl Compd 16, 225–226 (1980). https://doi.org/10.1007/BF02401713
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DOI: https://doi.org/10.1007/BF02401713