Skip to main content
SpringerLink
Log in

Acylation of 5-phenyl-2-(fur-2-yl)oxazole

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The ability of 5-phenyl-2-(fur-2-yl)oxazole to undergo acetylation and formylation is considered. It was established by x-ray structure analysis that electrophilic substitution proceeds at the position 5 of the furan ring. The direction of the reactions is analyzed from positions of the energy preference of transition states.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. B. M. Krasovitskii and B. M. Bolotin, Organic Luminophores [in Russian], Khimiya, Moscow (1984).

    Google Scholar 

  2. A. R. Katritzky, O. A. Schwarz, A. E. A. Rahman, and D. E. Leahy, J. Heterocycl. Chem.,21, 1673 (1984).

    CAS  Google Scholar 

  3. V. M. Shershukov, V. L. Volkov, and L. D. Patsenker, Ukr. Rep. Conf. on Organic Chemistry, Summary of Reports, Uzhgorod (1986), p. 357.

  4. V. M. Shershukov, L. D. Patsenker, and N. S. Pivnenko, Khim. Geterotsikl. Soedin., No. 6, 839 (1989).

    Google Scholar 

  5. A. F. Pozharskii, Theoretical Basis of the Chemistry of Heterocycles [in Russian], Khimiya, Moscow (1985).

    Google Scholar 

  6. I. A. Abronin and G. M. Zhidomirov, Khim. Geterotsikl. Soedin., No. 1, 3 (1977).

    Google Scholar 

  7. L. Pakett, Basis of the Recent Chemistry of Heterocyclic Compounds [Russian translation], Mir, Moscow (1971).

    Google Scholar 

  8. L. I. Belen'kii, Khim. Geterotsikl. Soedin., No. 12, 1587 (1980).

    Google Scholar 

  9. L. I. Belen'kii, G. P. Gromova, M. A. Cheskis, and Ya. L. Gol'dfarb, Chem. Scr.,25, 295 (1985).

    Google Scholar 

  10. M. J. S. Dewar and W. Thiel, J. Am. Chem. Soc.,99, 4899 (1977).

    CAS  Google Scholar 

  11. A. P. Shkumat, L. D. Patsenker, N. V. Adonina, and V. F. Lavrushin, Ukr. Khim. Zh.,53, 529 (1987).

    CAS  Google Scholar 

  12. G. M. Sheldrick, SHELXTL PLUS. PC Version. Siemens Analytical X-Ray Instruments Inc., Madison, Wisconsin (1989).

    Google Scholar 

Download references

Authors
  1. L. D. Patsenker
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. I. Lokshin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. G. Drushlyak
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. N. Baumer
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Institute of Monocrystals, Academy of Sciences (NAN) of Ukraine, Khar'kov 310001. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1466–1471, November, 1997.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Patsenker, L.D., Lokshin, A.I., Drushlyak, T.G. et al. Acylation of 5-phenyl-2-(fur-2-yl)oxazole. Chem Heterocycl Compd 33, 1266–1271 (1997). https://doi.org/10.1007/BF02320325

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02320325

Keywords

Search

Navigation