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Hexahydro-8-isoquinolones with electron-acceptor substituents in position 4

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

By the interaction of 2-acetyl-5,5-dimethyl-2-cyclohexen-1-one with certain nitroenamines, a number of hexahydro-8-isoquinolones with a nitro group in position 4 have been obtained; potentials of their electrochemical oxidation have been determined, and a possible mechanism and manifestation of structural effects in this process have been suggested and discussed. The structure of 1,3,6,6-tetramethyl-4-nitro-2, 4a-5,6,7,8-hexahydro-8-isoquinolone has been established by means of x-ray diffraction analysis.

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Authors
  1. Ya. Ozols
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  2. B. Vigante
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  3. L. Baumane
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  4. A. Mishnev
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  5. I. Turovskis
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  6. G. Duburs
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  7. Ya. Stradyn'
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Additional information

Latvian Institute of Organic Synthesis, Riga LV-11006. E-mail: aiva@osi.lanet.lv. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1372–1380, October, 1998.

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Ozols, Y., Vigante, B., Baumane, L. et al. Hexahydro-8-isoquinolones with electron-acceptor substituents in position 4. Chem Heterocycl Compd 34, 1166–1173 (1998). https://doi.org/10.1007/BF02319495

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  • DOI: https://doi.org/10.1007/BF02319495

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