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Chemistry of Heterocyclic Compounds

, Volume 33, Issue 5, pp 571–576 | Cite as

Oxidation reactions of azines.

4. Conjugation of 4-aryl-1,2,5,6-tetrahydropyridines with compounds containing an activated methyl group. Synthesis and structure of 2-acylmethylene-and 2-nitromethylene-1,2,5,6-tetrahydropyridines
  • A. T. Soldatenkov
  • I. A. Bekro
  • Zh. A. Mamyrbekova
  • S. A. Soldatova
  • É. Glover
  • N. D. Sergeeva
  • L. N. Kuleshova
  • V. N. Khrustalev
Article

Abstract

A novel Csp3−Csp3 oxidative conjugation with compounds containing an activated methylene group has been described in the case of 1-alkyl-4-aryl-1,2,5,6-tetrahydropyridines. It was shown that treatment of the indicated Δ3-piperidines with methyl ketones or nitromethane in the presence of KMnO4 gives their 2-acylmethylene-or 2-nitromethylene derivatives respectively.

Keywords

Oxidation Methyl Organic Chemistry Ketone Oxidation Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • A. T. Soldatenkov
  • I. A. Bekro
  • Zh. A. Mamyrbekova
  • S. A. Soldatova
  • É. Glover
  • N. D. Sergeeva
  • L. N. Kuleshova
  • V. N. Khrustalev

There are no affiliations available

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