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Reaction of 2-formyl-1,3-cyclanediones with N,N′-substituted 1,1-diamino-2-nitroethylenes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Reaction of 2-formyldimedone and 2-formyl-1,3-indanedione with 1,1-di(2-hydroxyethylamino)- and 1,1-di(4-morpholyl)-2-nitroethylenes produces 2-[3,3-di(2-hydroxyethylamino)-2-nitroprop-2-en-1-ylidene]- and 2-[3,3-di(4-morpholyl)-2-nitroprop-2-en-1-ylidene]-5,5-dimethyl-1,3-cyclohexanediones and the 1,3-indanediones, respectively. The reaction of the same 2-formyl-1,3-cyclanediones with 2-nitromethyleneimidazolidine yields 8,8-dimethyl-4-nitro-6-oxo-1,2,3,6,7,8-hexahydroimidazo[1,2-a]quinoline and 4-nitro-6-oxo-1,2-dihydro-6H-imidazo[1,2-c]-4-azafluorene.

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Riga Technical University, Riga LV-1658, Latvia; e-mail: marina@osi.lanet.lv. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 330–333, March, 1999.

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Strakov, A.Y., Petrova, M.V., Gurkovskii, A.I. et al. Reaction of 2-formyl-1,3-cyclanediones with N,N′-substituted 1,1-diamino-2-nitroethylenes. Chem Heterocycl Compd 35, 286–289 (1999). https://doi.org/10.1007/BF02259356

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  • DOI: https://doi.org/10.1007/BF02259356

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