Skip to main content
SpringerLink
Log in

Synthesis of thienylhydrogermanes and their transformations in the presence of di(tert-butyl) peroxide

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A method was developed for the synthesis of thienylhydrogermanes RnGeH4−n (where R=2-thienyl, n=1–3), involving the reduction of the corresponding ethoxygermanes by lithium aluminum hydride under the conditions of phase-transfer catalysis. The transformations of thienylhydrogermanes under the influence of di(tert-butyl) peroxide were studied. Features of the mass-spectrometric behavior of thienylethoxygermanes were analyzed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. Ya. Lukevics, O. A. Pudova, and N. P. Erchak, Advances in Organosilicon Chemistry, MIR Publishers, Moscow (1985), p. 153.

    Google Scholar 

  2. E. Lukevics, R. Ya. Sturkovich, and O. A. Pudova, J. Organomet. Chem.,292, 151 (1985).

    Article  Google Scholar 

  3. E. Lukevics, O. A. Pudova, R. Ya. Sturkovich, and A. P. Gaukhman, J. Organomet. Chem.,346, 297 (1988).

    Article  Google Scholar 

  4. E. Lukevits [Lukevics], R. Ya. Sturkovich, and O. A. Pudova, Zh. Obshch. Khim.,58, 815 (1988).

    Google Scholar 

  5. E. Lukevics, S. Belyakov, and O. Pudova, J. Organomet. Chem.,523, 41 (1996).

    Article  Google Scholar 

  6. E. Lukevits [Lukevics], S. Germane, O. A. Pudova, and N. P. Erchak, Khim. Farm. Zh.,13, No. 10, 52 (1979).

    Google Scholar 

  7. E. Lukevics, L. Ignatovich, N. Porsiurova, and S. Germane, Appl. Organomet. Chem.,2, 115 (1988).

    Article  Google Scholar 

  8. V. N. Gevorgyan, L. M. Ignatovich, and E. Lukevics, J. Organomet. Chem.,284, C31 (1985).

    Article  Google Scholar 

  9. V. Gevorgyan and E. Lukevics, J. Chem. Soc. Chem. Commun., No. 18, 1234 (1985).

    Article  Google Scholar 

  10. S. Kh. Rozite, I. B. Mazheika, A. P. Gaukhman, N. P. Erchak, and E. Lukevits [Lukevics], Izv. Akad. Nauk Latv. SSR. Ser. Khim., No. 1, 102 (1985).

    Google Scholar 

  11. I. Mazheika, S. Grinberg, and E. Lukevits [Lukevics], Khim. Geterotsikl. Soedin., No. 7, 891 (1993).

    Google Scholar 

  12. E. Lukevits [Lukevics], O. A. Pudova, L. I. Borisova, and V. N. Gevorgyan, Izv. Akad. Nauk Latv. SSR. Ser. Khim., No. 5, 597 (1989).

    Google Scholar 

Download references

Authors
  1. E. Lukevics
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. A. Pudova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. Mazheika
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. Grinberga
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Latvian Institute of Organic Synthesis, Riga. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 198–201, February, 1997.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lukevics, E., Pudova, O.A., Mazheika, I. et al. Synthesis of thienylhydrogermanes and their transformations in the presence of di(tert-butyl) peroxide. Chem Heterocycl Compd 33, 171–174 (1997). https://doi.org/10.1007/BF02256758

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02256758

Keywords

Search

Navigation