Abstract
The reaction of potassium salt of 5-(2,4-dichlorophenyl)-1,3,4-oxadiazoline-2-thione with dimethyl sulfate was carried out in water and HMPT. It was shown that the nature of the solvent affects the ratio of the formed products of S- and N-methylation. The alkylation of 5-aryl-1,3,4-oxadiazoline-2-thiones with isomeric butyl chlorides showed that the reaction takes place only with n-butyl chloride with the formation of the corresponding S-butyl-substituted derivative.
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Institute of the Chemistry of Vegetable Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent 700170. Translated from Khimiya Geterotsikliheskikh Soedinenii, No. 9, pp. 1268–1270, September, 1997.
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Ziyaev, A.A., Galust'yan, G.G. Direction of alkylation of 5-aryl-1,3,4-oxadiazoline-2-thiones. Chem Heterocycl Compd 33, 1109–1111 (1997). https://doi.org/10.1007/BF02253229
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DOI: https://doi.org/10.1007/BF02253229