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Chromatographic/mass-spectrometric analysis of heterocyclic tautomeric forms of nitrogen-containing derivatives of 1,3-dicarbonyl compounds

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

By means of chromatography/mass spectrometry, a quantitative estimate has been made of the gas-phase contents of different tautomeric forms of a monooxime, monoacetylhydrazone, diacetylhydrazone, and monoamidrazonoacetylacetone. In particular, individual tautomeric forms of these compounds were identified: 5-hydroxyoxazoline, 5-hydroxypyrazoline, 5-hydroxylaminopyrazoline, 5-acetylhydrazinylpyrazoline, and 5-acetonyl-2,3,4-triazoline.

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Authors
  1. P. B. Terent'ev
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  2. A. G. Kalandarishvili
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  3. K. N. Zelenin
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  4. O. V. Solod
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  5. V. K. Shevtsov
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Additional information

We dedicate this article to the memory of I. N. Goncharova.

M. V. Lomonosov Moscow State University, Moscow 119899. Military Medical Academy, St. Petersburg 194175. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp 1228–1236, September, 1997.

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Terent'ev, P.B., Kalandarishvili, A.G., Zelenin, K.N. et al. Chromatographic/mass-spectrometric analysis of heterocyclic tautomeric forms of nitrogen-containing derivatives of 1,3-dicarbonyl compounds. Chem Heterocycl Compd 33, 1070–1077 (1997). https://doi.org/10.1007/BF02253222

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  • DOI: https://doi.org/10.1007/BF02253222

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