Abstract
By reactions of substituted chloropyrimidines with the sodium salt of 2,2-dimethyltetrahydro-4-pyranone oxime, pyrimidinyloximes of 2,2-dimethyltetrahydro-4-pyranone have been obtained. On the basis of x-ray diffraction studies of the O-(2,4-dimethyl-6-pyrimidinyl)oxime of 2,2-dimethyltetrahydro-4-pyranone, it has been shown that the oxygen atoms of the oxime group and the carbon in position 2 of the pyran ring are in theanti position relative to the double bond of the oxime.
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Erevan Institute of the National Economy, Erevan 375025. Molecular Structure Research Center, National Academy of Sciences of the Republic of Armenia, Erevan 375014. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 957–961, July, 1997.
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Danagulyan, G.G., Karapetyan, A.A., Zalinyan, M.G. et al. Synthesis and structure of certain O-pyrimidinyl-oximes of 2,2-dimethyltetrahydro-4-pyranone. Chem Heterocycl Compd 33, 838–842 (1997). https://doi.org/10.1007/BF02253036
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DOI: https://doi.org/10.1007/BF02253036