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Synthesis, structure, spectral, and electrochemical properties of the Au(I) complex with 5-methoxy-8-(N-picrylamino)quinoline

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The synthesis of a gold(I) chelate complex obtained from an autocomplex of the picryl series with a quinoline-containing donor fragment is described. The crystal structure was established by X-ray analysis, the spectral and electrochemical properties were studied. The molecules of the complex obtained have a conformation in which both o-NO2 groups of the picryl fragment participate in intramolecular charge transfer by contact.

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Authors
  1. K. I. Grandberg
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  2. L. G. Kuz'mina
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  3. G. G. Aleksandrov
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  4. I. G. Il'ina
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  5. O. V. Mikhalev
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  6. R. D. Rakhimov
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  7. K. P. Butin
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Additional information

M. V. Lomonosov Moscow State University, Moscow 119899, Russia. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1028–1035, August, 1999.

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Grandberg, K.I., Kuz'mina, L.G., Aleksandrov, G.G. et al. Synthesis, structure, spectral, and electrochemical properties of the Au(I) complex with 5-methoxy-8-(N-picrylamino)quinoline. Chem Heterocycl Compd 35, 900–906 (1999). https://doi.org/10.1007/BF02252157

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  • DOI: https://doi.org/10.1007/BF02252157

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