Abstract
Methods have been developed for dehydrating the unusually stable intermediate products of the Hantzsch reaction of N,N′-diphenylthioureas with derivatives of phenylchloropyruvic acid, viz. 4-hydroxy-4-methoxy (diethylamino)carbonyl-3,5-diphenyl-2-phenyliminothiazolidines, into the corresponding 4-methoxy-(diethylamino) carbonyl-3,5-diphenyl-2-phenyliminothiazolines. Characteristic features of the dissociative ionization of the latter and their anilide analog under the action of electron impact have been clarified.
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A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan 420088; Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1561–1567, November, 1999.
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Mamedov, V.A., Nurkhametova, I.Z., Rizvanov, I.K. et al. Derivatives of 4-carboxy-3,5-diphenyl-2-phenyliminothiazoline. Synthesis and mass spectral investigation. Chem Heterocycl Compd 35, 1364–1369 (1999). https://doi.org/10.1007/BF02252010
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DOI: https://doi.org/10.1007/BF02252010