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Heterocyclization reaction of propargyl acetate with β-dicarbonyl compounds

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The regiochemistry of the reaction of propargyl acetate with CH acids in the presence of mercury(II) acetate in dimethylsulfoxide has been investigated. Derivatives of furan or unsaturated diketones were isolated depending on the nature of the 1,3-dicarbonyl and the possibility of reduction of the organomercury intermediate.

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Institute of Organic Chemistry, Armenian National Academy of Sciences, Erevan 375091. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 904–907, July, 1998.

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Badanyan, S.O., Chobanyan, Z.A., Tirakyan, M.R. et al. Heterocyclization reaction of propargyl acetate with β-dicarbonyl compounds. Chem Heterocycl Compd 34, 781–784 (1998). https://doi.org/10.1007/BF02251682

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  • DOI: https://doi.org/10.1007/BF02251682

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