Abstract
The oxidation of furfural by an aqueous solution of hydrogen peroxide in the presence of sodium molybdate was studied for the first time. Its final products are 2(5H)-furanone and also tartaric, malic, and succinic acids. The process takes place through the formation of peroxide and carbonyl compounds. Kinetic curves for the consumption of the reagents and the accumulation of the reaction products were obtained. In direction oxidation in this system differs substantially from the previously studied reactions of furfural with an aqueous solution of hydrogen peroxide without a catalyst and in the presence of selenium and vanadium compounds.
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References
V. V. Poskonin, L. A. Badovskaya, and L. V. Povarova, Khim. Geterotsikl. Soedin., No. 7, 893 (1998).
V. G. Kul'nevich and L. A. Badovskaya, Usp. Khim.,44, 1256 (1975).
G. F. Musychenko, L. A. Badovskaya, and V. G. Kul'nevich, Khim. Geterotsikl. Soedin., No. 11, 1453 (1972).
L. A. Badovskaya, T. Ya. Kaklyugina, and V. G. Kul'nevich, Khim. Geterotsikl. Soedin., No. 5, 603 (1977).
G. D. Krapivin, O. P. Yablonskii, É. G. Chkalova, L. A. Badovskaya, and V. G. Kul'nevich, Zh. Fiz. Khim.,50, 1399 (1972).
V. M. Latashko, Thesis for Candidate of Chemical Sciences [in Russian], Krasnodar (1975).
L. A. Badovskaya, Thesis for Doctor of Chemical Sciences [in Russian], Krasnodar (1982).
S. P. Gavrilova, Author's Abstract of Candidate's Thesis [in Russian], Krasnodar (1980).
V. V. Poskonin and L. A. Badovskaya, Khim. Geterotsikl. Soedin., No. 11, 1462 (1991).
S. P. Gavrilova, L. A. Badovskaya, and V. G. Kul'nevich, Kinet. Katal.,20, 1338 (1979).
H. Mimoun, J. Seree de Roch, and L. Sajus, Bull. Soc. Chim. France, No. 5, 1481 (1969).
I. P. Skibida, Usp. Khim.,44, 1729 (1975).
I. V. Spirina, V. P. Maslennikov, and Yu. A. Aleksandrov, Usp. Khim.,56, 1167 (1987).
I. I. Moiseev and M. N. Vargaftik, Usp. Khim.,59, 1931 (1990).
G. A. Tolstikov, Hydroperoxide Oxidation Reactions [in Russian], Nauka, Moscow (1976).
H. M. Dickman and M. T. Pope, Chem. Rev.,94, 569 (1994).
R. A. Sheldon and J. K. Kochi, Metal-Catalyzed Oxidation of Organic Compounds, Interscience, New York (1981).
C. Djordjevic, N. Vuletic, and E. Sinn, Inorg. Chim. Acta,104, 17 (1985).
V. Conte, F. Di Furia, G. Modena, and O. Bortolini, J. Org. Chem.,53, 4581 (1988).
S. Sankar, R. Maurya, and R. Sabharwal, Curr. Sci.,47, 341 (1978).
M. I. Bulatov and I. P. Kalinkin, Practical Manual of Photometric Methods of Analysis [in Russian], Khimiya, Leningrad (1986), p. 359.
L. A. Badovskaya and V. G. Kul'nevich, Zh. Anal. Khim.,22, 271 (1967).
L. A. Badovskaya, R. R. Vysyukova, and V. G. Kul'nevich, Zh. Anal. Khim.,22, 1268 (1967).
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For Communication 3, see [1].
Kubansk State Technological University, Krasnodar 350072, Russia. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 898–903, July, 1998.
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Grunskaya, E.P., Badovskaya, L.A., Poskonin, V.V. et al. Catalytic oxidation of furan and hydrofuran compounds. 4. Oxidation of furfural by hydrogen peroxide in the presence of sodium molybdate. Chem Heterocycl Compd 34, 775–780 (1998). https://doi.org/10.1007/BF02251681
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DOI: https://doi.org/10.1007/BF02251681