Skip to main content
Log in

Experimental and theoretical results on palladium-catalyzed hydrogenation reactions

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

A correlation between the stereoselectivity of cis-and trans-1, 2-dimethylcyclohexane in o-xylene hydrogenation and theoretical charge density of Pd centers as a function of particle size has been established.

Abstract

Определена зависимость стереоселективности дис — и транс-1, 2-диметилциклогексана в гидрогенизации o-ксилола и теореической плотности зарядов Pd центров от размера частиц.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Rererences

  1. M. Viniegra, G. Cordoba, R. Gomez: J. Mol. Catal.,58, 107 (1990); R. Gomez, G. del Angel, V. Bertin: React. Kinet. Catal. Lett. (in press).

    Google Scholar 

  2. C. Jarque, O. Novaro, M.E. Ruiz, J. Garcia-Prieto: J. Am. Chem. Soc.,108, 3507 (1986); O. Novaro: “Activation of Small Molecules by Transition Metal Atoms”, Chapter 8 in the book “The Challenge of d- and f-Electrons”, D.R. Salahub and M. Zerner editors (Amer. Chem. Soc. Ser. 1989); O. Novaro, C. Jarque: Theor. Chim. Acta (in press).

    Google Scholar 

  3. P. Chou, M.A. Vannice: J. Catal.,104, 1 (1987).

    Google Scholar 

  4. G.A. Ozin, J. Garcia-Prieto: J. Amer. Chem. Soc.,108, 3099 (1986).

    Google Scholar 

  5. J. Garcia-Prieto, O. Novaro: Internat. J. Quantum Chem.,18, 599 (1980).

    Google Scholar 

  6. O. Novaro, W. Kolos: J. Chem. Phys.,67, 5066 (1977).

    Google Scholar 

  7. M.P. Guse, R.J. Blint, A.B. Kunz: Internat. J. Quantum Chem.,11, 725 (1977); E. Miyoshi, Y. Sakai, S. Mori: Surface Sci.,158, 667 (1985).

    Google Scholar 

  8. R.C. Baetzold: J. Am. Chem. Soc.,82, 738 (1978).

    Google Scholar 

  9. Work in progress.

Download references

Author information

Authors and Affiliations

Authors

Additional information

On sabbatical leave from Instituto de Fisica UNAM.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gomez, R., Novaro, O. Experimental and theoretical results on palladium-catalyzed hydrogenation reactions. React Kinet Catal Lett 45, 251–256 (1991). https://doi.org/10.1007/BF02070435

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02070435

Keywords

Navigation