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Mechanism of isotope exchange of dihydrogen with liquid water catalyzed by hydroxide ions

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Abstract

In the analysis of the reaction between dissolving hydrogen and aqueous alkali hydroxide solutions the interaction of hydrogen with the molecular ion (H3O2)− should be studied. This interaction is analyzed by the interacting bonds method. The activation energy (Ea) is estimated.

Abstract

Обращается внимание на то, что при анализе химического взаимодействия растворяющегося водорода с водным раствором щёлочи необходимо рассматривать взаимодействие водорода с молекулярным ионом (H3O2)−. Проводится анализ этого взаимодействия методом взаимодействующих связей. Осуществлена оценка энергии активации (Ea).

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Authors and Affiliations

  1. Polytechnical Institute, Tomsk, USSR

    A. A. Medvinskii, N. N. Bulgakov, Yu. M. Baikov, G. G. Saveliev & E. K. Shalkova

  2. Institute of Catalysis, Novosibirsk, USSR

    A. A. Medvinskii, N. N. Bulgakov, Yu. M. Baikov, G. G. Saveliev & E. K. Shalkova

  3. Physico-Technical Institute, Leningrad, USSR

    A. A. Medvinskii, N. N. Bulgakov, Yu. M. Baikov, G. G. Saveliev & E. K. Shalkova

Authors
  1. A. A. Medvinskii
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  2. N. N. Bulgakov
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  3. Yu. M. Baikov
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  4. G. G. Saveliev
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  5. E. K. Shalkova
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Medvinskii, A.A., Bulgakov, N.N., Baikov, Y.M. et al. Mechanism of isotope exchange of dihydrogen with liquid water catalyzed by hydroxide ions. React Kinet Catal Lett 17, 203–207 (1981). https://doi.org/10.1007/BF02065820

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  • DOI: https://doi.org/10.1007/BF02065820

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