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Mechanism of competitive oxidation and H-D exchange of cyclohexane in the PtII−PtIV−Cl−−D2O−D2SO4 system

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Abstract

The results of kinetic studies on competitive oxidation and H-D exchange of cyclohexane in the PtII−PtIV−Cl−−D2O−D2SO4 system involving variations in the concentrations of D+, Cl− and PtII, are in agreement with two possible mechanisms involving the formation of a common intermediate alkyl-platinum complex.

Abstract

Изучена кинетика конкурирующих реакций окисления и H/D обмена циклогексана в системе PtII−PtIV−Cl−−D2O−D2SO4 при изменении концентраций D+, Cl−, PtII Результаты согласуются с двумя возможными механизмами, вклюгающими образование промежутогного платинаалкильного комплекса-общего ддя окисдения и обмена.

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References

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Authors and Affiliations

  1. Institute of Physical Organic and Coal Chemistry, Donetsk, USSR

    V. P. Tretyakov, E. S. Rudakov, S. A. Mitchenko, A. V. Bogdanov & L. A. Minko

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  1. V. P. Tretyakov
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  2. E. S. Rudakov
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  3. S. A. Mitchenko
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  4. A. V. Bogdanov
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  5. L. A. Minko
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Tretyakov, V.P., Rudakov, E.S., Mitchenko, S.A. et al. Mechanism of competitive oxidation and H-D exchange of cyclohexane in the PtII−PtIV−Cl−−D2O−D2SO4 system. React Kinet Catal Lett 17, 197–201 (1981). https://doi.org/10.1007/BF02065819

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  • DOI: https://doi.org/10.1007/BF02065819

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