Abstract
The conceptual foundations of the modern thermodynamic theory related to a large category of far-from-equilibrium phenomena are outlined, and the historical continuity with early developments based on the impossibility of perpetual motion is discussed.
In this perspective the discovery of thermodynamic stability criteria around steady or periodic processes, together with a general evolution criterion that is valid in the non-linear region (and thus implying creation of order and applicability to living systems), appears as a most remarkable development indeed. The leading role played by the Brussels school and particularly by Ilya Prigogine is emphasized.
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References
I. Prigogine,Étude thermodynamique des phénomènes irreversibles (Thèse, Bruxelles, 1945) (Desoer, Liège, 1947).
I. Prigogine and R. Defay,Chemical Thermodynamics (translated by D. H. Everett)(Longmans, Green and Company, London, 1954).
I. Prigogine,Introduction to Thermodynamics of Irreversible Processes (Thomas, New York, 1955; Wiley, New York, 1977).
Actes de la table ronde,Sadi Carnot et l'essor de la thermodynamique. I. English texts: C. C. Gillispie, J. Herivel, R. McKeon, R. Fox, E. Mendoza, P. Schereschewsky, P. Lerving, and M. Klein. French texts: R. Taton, A. Birembaut, P. Costabel, J. Payen, A. Kastler, U. Hoyer, H. Kangro, and M. Sadoun Goupil.
Sadi Carnot,Reflexions sur la puissance motrice du feu et sur les machines propres à développer cette puissance (Bachelier, Paris, 1824; Blanchard, Paris, 1953); translated by R. H. Thursten and reprinted inReflections on the Motive Power of Fire and Other Papers on the Second Law of Thermodynamics, E. Mendosa, ed. (New York, 1960). See also Ref. 4, M. Klein, p. 214.
R. Clausius,Die mechanische Wärmetheorie, 3rd edn. (Braunschweig, 1887);Pogg. Ann. CXXV, 400 (1865).
J. W. Gibbs,Collected Works: Equilibrium of Heterogeneous Substances, 1875–1878 (Longmans and Green, New York, 1931).
I. Prigogine, inBoltzmann Equation: Theory and Applications, E. G. D. Cohen and W. Thirring, eds. (Springer, New York, 1973).
I. Prigogine, “Dissipative structures, dynamics and entropy,”International Journal of Quantum Chemistry Symposium No.9 (Wiley, New York, 1975), pp. 443–456.
P. Duhem,Traité d'énergétique ou de thermodynamique générale (Gauthier-Villars, Paris, 1911).
L. Onsager,Phys. Rev. 37, 405, 1931.
S. R. De Groot and P. Mazur,Non-Equilibrium Thermodynamics (North-Holland, Amsterdam, 1962).
P. Glansdorff and I. Prigogine,Physica 20, 773 (1954);30, 351 (1964).
P. Glansdorff and I. Prigogine,Thermodynamics of Structure, Stability and Flucturations (Wiley-Interscience, London, New York, 1971).
G. Nicolis and I. Prigogine,Self-Organization in Nonequilibrium Systems (Wiley-Interscience, New York, 1977).
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Glansdorff, P. Irreversibility in macroscopic physics: From Carnot cycle to dissipative structures. Found Phys 17, 653–666 (1987). https://doi.org/10.1007/BF01889539
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DOI: https://doi.org/10.1007/BF01889539