Skip to main content
SpringerLink
Log in

Reaction of 2-chloromethylbenzimidazoles with acetylacetone and benzoylacetone. Basic breakdown ofβ-diketones

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Base treatment of the products of alkylation ofβ-diketones by 2-chloromethylbenzimidazole under phase transfer catalysis (PTC) conditions causes loss of the acetyl group and formation of methylethyl- or ethylphenyl ketones.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. I. I. Popov, Khim. Geterotsikl. Soedin., No. 5, 664 (1993).

  2. W. Weber and G. Gokel, Phase Transfer Catalysis in Organic Synthesis [Russian translation], Mir, Moscow (1980), p. 220.

    Google Scholar 

  3. H. Walba, W. L. Murray, Y. Knitson, and A. Diaz, J. Am. Chem. Soc.,88, 1622 (1966).

    Google Scholar 

Download references

Authors
  1. I. I. Popov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Rostov State University, Rostov-on Don 344090. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1067–1071, August, 1996. Original article submitted March 25, 1996.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Popov, I.I. Reaction of 2-chloromethylbenzimidazoles with acetylacetone and benzoylacetone. Basic breakdown ofβ-diketones. Chem Heterocycl Compd 32, 918–922 (1996). https://doi.org/10.1007/BF01176967

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01176967

Keywords

Search

Navigation