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Mass-spectrometric behavior of isatin oximes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

On the basis of an analysis of the mass spectra of a large series of benzo-substituted isatin oximes it is shown that their molecular ions undergo type II Beckmann rearrangment to the corresponding o-N-carboxyaminobenzonitriles.

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Authors and Affiliations

  1. Kaunas Medical Institute, 233007, Kaunas

    P. B. Terent'ev, L. I. Mazhilis, A. G. Kalandarishvili & A. P. Stankyavichus

  2. M. V. Lomonosov Moscow State University, 117234, Moscow

    P. B. Terent'ev, L. I. Mazhilis, A. G. Kalandarishvili & A. P. Stankyavichus

Authors
  1. P. B. Terent'ev
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  2. L. I. Mazhilis
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  3. A. G. Kalandarishvili
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  4. A. P. Stankyavichus
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1052–1055, August, 1986.

The authors thank N. A. Klyuev for his assistance in recording the high-resolution mass spectra.

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Terent'ev, P.B., Mazhilis, L.I., Kalandarishvili, A.G. et al. Mass-spectrometric behavior of isatin oximes. Chem Heterocycl Compd 22, 848–851 (1986). https://doi.org/10.1007/BF01175057

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  • DOI: https://doi.org/10.1007/BF01175057

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