Abstract
Methyl derivatives of several nitrogen-containing heterocyclic compounds were converted into the corresponding carboxylic acids by means of electrochemical oxidation at the nickel oxohydroxide anode in alkaline medium, using a nondiaphragm electrolyzer. The oxidation of 2,5-dimethylpyrazine was used to demonstrate the effect of adding chromium (III) and cobalt (II) compounds to the reaction mixture. The composition and electronics state of the anode surface were studied usign x-ray diffraction and XPS methods.
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Feldman, D., Chervenka, M., Stokh, E. et al. Anodic oxidation of methyl-substituted nitrogen-containing heterocyclic compounds at the. Chem Heterocycl Compd 31, 80–85 (1995). https://doi.org/10.1007/BF01171298
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DOI: https://doi.org/10.1007/BF01171298