Abstract
Pyrrole-2-dithiocarboxylates were obtained by reacting alkylpyrroles with carbon disulfide in the presence of alkyl halides in the KOH-DMSO system. The pyrrole and its aryl derivatives were primarily converted into pyrrole-1-dithiocarboxylates in these conditions. The electronic structure and redox properties of the synthesized compounds were investigated by polarography and cyclic voltammetry.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
V. N. Drozd, M. L. Petrov, N. Ya. Kuz'mina, and A. S. Vyagin, Usp. Khim.,57, 94 (1988).
Y. Tominaga, Y. Matsuoka, Y. Oniyama, Y. Uchimura, H. Komiya, M. Hirayama, S. Kohra, and A. Hosomi, J. Heterocycl. Chem.,27, 647 (1990).
A. R. Katritzky, Ch. V. Marson, and H. Faid-Allah, Heterocycles,26, 1657 (1987).
S. Kato and M. Ishida, Sulfur Repts.,8, 155 (1988).
B. A. Trofimov L. N. Sobenina, A. I. Mikhaleva, M. P. Sergeeva, N. I. Golovanova, R. I. Polovnikova, and A. N. Vavilova, Khim. Geterotsikl. Soedin., No. 9, 1176 (1991).
S. A. Trofimov, L. N. Sobenina, A. I. Mikhaleva, M. P. Sergeeva, and N. I. Polovnikova, Sulfur Lett.,15, 219 (1992).
A. Kreutzberger and P. Kalter, J. Phys. Chem.,65, 624 (1961).
B. A. Trofimov, V. B. Modonov, T. N. Aksamentova, A. I. Mikhaleva, S. E. Korostova, A. N. Vasil'ev, L. N. Sobenina, and R. N. Nesterenko, Zh. Obshch. Khim.,53, 1867 (1983).
R, Mayer, in: Sulfur in Organic and Inorganic Chemistry, A. Senning (ed.), Vol. 3, New York (1992), p. 305.
R. L. Glicksman, J. Electrochem. Soc.,110, 353 (1963).
H. Lund, Coll. Czech. Chem. Commun.,25, 3313 (1960).
A. M. Bond, A. R. Hendrichson and R. L. Martin, J. Electrochim. Soc., 119, 1325 (1972).
S. Scheithaner and R. Mayer, in: Topics in Sulfur Chemistry, A. Senning (ed.), Vol, 4, Thieme, Stuttgart (1979).
A. T. Tomilov and I. N. Chernykh, Electrochemistry of Organoelemental Compounds (Elements of Groups IV, V, and VI of the Periodic System) [in Russian], Nauka, Moscow (1986).
J. Voss and K. Thinnk, Tetrahedron,33, 259 (1977).
I. M. Kolotyrkin (ed.). Electrochemistry of Metals in Nonaqueous Solutions [Russian translation], Mir, Moscow (1974).
Author information
Authors and Affiliations
Additional information
Translated from Khimiya Geterotsiklicheskikh Soedinenii. No. 1, pp. 47–54, January, 1995.
Rights and permissions
About this article
Cite this article
Sobenina, L.N., Protasova, L.E., Sergeeva, M.P. et al. Synthesis and redox properties of pyrroledithiocarboxylic acid esters. Chem Heterocycl Compd 31, 40–46 (1995). https://doi.org/10.1007/BF01171288
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01171288