Abstract
Treatment of 2-(N-potassium-N-cyanamino)-4,6-dimethylpyrimidine with ethyliodoacetate produces 2-(N-cyano-N-carbethoxymethylamino)-4,6-dimethylpyrimidine. Alkaline hydrolysis of the last gives 2-(3-potassium-2,4-dioxoimidazolidinyl-1)-4,6-dimethylpyrimidine. Ammonolysis and hydrazinolysis give imino- or amino-imidazolidinylpyrimidine, respectively.
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References
D. J. Brown, The Pyrimidines, Interscience Pubs., New York-London (1962).
S. Birtwell, J. Chem. Soc., 1725 (1953).
V. V. Dovlatyan, L. A. Khachatryan, and É/ Ambartsumyan, Arm. Khim. Zh., No. 4, 311, (1980).
V. V. Dovlatyan, L. A. Khachatryan, and É. Ambartsumyan, Arm. Khim. Zh., No. 12, 799 (1982)
V. V. Dovlatyan, É. N. Ambartsumyan, and L. M. Gyul'budagyan, Arm. Khim. Zh., No. 5, 322 (1982).
V. V. Dovlatyan, É. N. Ambartsumyan, L. M. Gyul'budagyan, and R. G. Mirzoyan, Khim. Geterotsikl. Soedin., No. 6, 817
G. S. Amazaspyan, É. N. Ambartsumyan, and V. V. Dovlatyan, Arm. Khim. Zh., No. 11 710 (1990).
V. V. Dovlatyan, K. A. Éliazyan, V. V. Pivazyan, and A. M. Akopyan. Khim. Geterotsikl. Soedin., No. 6, 818 (1993).
V. V. Dovlatyan, É. N. Ambartsumyan, and L. M. Gyul'budagyan, and G. S. Amazaspyan, Khim. Geterotsikl. Soedin., No. 8, 1114 (1993).
H. Ritthausen, Ber.,29, 2108 (1896).
Additional information
Armenian Agricultural Institute, Erevan 375009. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1239–1241, September, 1994. Original article submitted August 9, 1994.
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Dovlatyan, V.V., Éliazyan, K.A. & Pivazyan, V.A. Functionally substituted azines. 1. Synthesis and reactions of 2-(N-cyano-N-carbethoxmethylamino)-4,6-dimethylpyrimidine. Chem Heterocycl Compd 30, 1074–1076 (1994). https://doi.org/10.1007/BF01171168
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DOI: https://doi.org/10.1007/BF01171168