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Saturated nitrogen-containing heterocycles. 17. Synthesis and catalytic hydrogenation of 9,10-substituted decahydroacridines (mechanism of hydroamination ofβ-cycloketols)

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Abstract

The synthesis of 9, 10-substituted decahydroacridines was carried out, and their catalytic hydrogenation was studied. The participation of these compounds as intermediates in the formation of perhydroacridines in the reaction of catalytic hydroamination of 8-R-2-hydroxy-13-oxotricyclo[7.3.1.02.7]tridecanes was established. The1H and13C NMR spectra of the synthesized compounds are given.

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N. G. Chernyshevskii Saratov State University. Saratov 410601. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 945–949, July, 1995. Original article submitted February 28, 1995.

For report 16, see [1]

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Nikolaeva, T.G., Poddubnyi, I.S. & Kriven'ko, A.P. Saturated nitrogen-containing heterocycles. 17. Synthesis and catalytic hydrogenation of 9,10-substituted decahydroacridines (mechanism of hydroamination ofβ-cycloketols). Chem Heterocycl Compd 31, 823–826 (1995). https://doi.org/10.1007/BF01170743

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