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Crystal structure of 1-[N-2-aminoethyl)-aminopropyl]silatrane

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Abstract

The crystal structure of 1-[N-(2-aminoethyl)aminopropyl]silatrane has been determined by x-ray diffraction at room temperature. The Si←N bond distance (2.165(2) Å) is in the range observed for other 1-X-propylsilatranes (X = CN, OH, SH, Cl and SCN). The structure is partially disordered: the silatrane moiety displays a disorder that is typical for silatranes and the aminoethyl group terminating the planar chain linked to silicon is rotationally disordered.

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Authors and Affiliations

  1. Institute for Inorganic Chemistry, Technical University of Budapest, H-1521, Budapest, Hungary

    P. Hencsei

  2. Central Research Institute for Chemistry, Hungarian Academy of Sciences, P.O. Box 17, H-1525, Budapest, Hungary

    L. Párkányi

  3. Georgikon University, Keszthely, Deák u. 16, H-8360, Hungary

    I. Kovács

Authors
  1. P. Hencsei
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  2. L. Párkányi
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  3. I. Kovács
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Additional information

Dedicated to Professor Dr. Édmund Lukevits on the occasion of his 60th birthday.

Published in Khimiya Geterotsklicheskikh Soedinenii, Nos. 11–12, pp. 1600–1604, November–December, 1996. Original article submitted September 25, 1996.

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Hencsei, P., Párkányi, L. & Kovács, I. Crystal structure of 1-[N-2-aminoethyl)-aminopropyl]silatrane. Chem Heterocycl Compd 32, 1376–1380 (1996). https://doi.org/10.1007/BF01169968

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  • DOI: https://doi.org/10.1007/BF01169968

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